Reduction of CS2 to an ethanetetrathiolate by a hydride-bridged uranium-iridium heterobimetallic complex

被引：0

作者：

Ye, Christopher Z. ^{[1
,2
]}

Del Rosal, Iker ^{[3
]}

Ouellette, Erik T. ^{[1
,2
]}

Hohloch, Stephan ^{[4
]}

Maron, Laurent ^{[3
]}

Camp, Clement ^{[5
]}

Arnold, John ^{[1
,2
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA

[3] Univ Toulouse, CNRS, UMR 5215, LPCNO,INSA,UPS, 135 Ave Rangueil, F-31077 Toulouse, France

[4] Univ Paderborn, Warburger Str 100, D-33098 Paderborn, Germany

[5] Univ Claude Bernard Lyon 1, Inst Chim Lyon, Lab Catalysis Polymerizat Proc & Mat CP2M, CPE Lyon,UMR 5128,CNRS, 43 Bvd 11 Novembre 1918, F-69616 Villeurbanne, France

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 85期

关键词：

CRYSTAL-STRUCTURE; CARBON-DISULFIDE; REACTIVITY; CO2; INSERTION; ALKYL; TANTALUM/IRIDIUM; BOROHYDRIDE; CHEMISTRY; LIGANDS;

D O I：

10.1039/d4cc02482f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis of a heterobimetallic U(iii)-Ir species which reacts with CS2 to form the novel ethanetetrathiolate fragment via hydride insertion and C-C coupling. Computational studies suggest the formation of a radical intermediate, which may couple with another equivalent to form the final product.

引用

页码：12377 / 12380

页数：4

共 19 条

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