Inhibition of potassium ions on hydration swelling of montmorillonite

被引:0
|
作者
Xu Z.-Q. [1 ]
Liu J. [1 ]
Wang H.-F. [1 ]
Zhang Z.-J. [1 ]
机构
[1] School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing
来源
关键词
Hydration swelling; Inhibition; Montmorillonite; Potassium ions;
D O I
10.13225/j.cnki.jccs.2015.0486
中图分类号
学科分类号
摘要
Montmorillonite is the main factor affecting the settling performance of coal slime water, static settling tests and pressure filtration experiments were designed to study inhibition of potassium ions on hydration swelling of montmorillonite. Volume expansion of montmorillonite in deionized water is 2.3 times greater than the original volume of dry powder, while the volume expansion of montmorillonite in the solution of 0.1 mol/L potassium ions is only 1.8 times greater than the original volume. The filtering speed of montmorillonite in the solution of potassium ions is obviously faster than that in deionized water. Hydration swelling of montmorillonite could be inhibited by potassium ions, and Inhibitive effect of potassium ions on hydration swelling of montmorillonite is better than calcium ions. The inhibitive mechanism of potassium ions on hydration swelling of montmorillonite is that the potassium ion was adsorbed on montmorillonite interlayer, potassium ion is not easy to hydration, the water molecules between the crystal layer is discharged, and the bonding layer between the potassium ions greatly restrain the expansion or separation process of adjacent crystal layers. © 2016, China Coal Society. All right reserved.
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页码:464 / 468
页数:4
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共 15 条
  • [1] Duong C., Choung J., Xu Z., Et al., A novel process for recovering clean coal and water from coal tailings, Mineral Engineering, 13, 2, pp. 173-181, (2000)
  • [2] Lin Z., Yang C., Shen Z., Et al., The properties and sedimentation characteristics of extremely sliming coal slime water, Journal of China Coal Society, 35, 2, pp. 312-315, (2010)
  • [3] Zhang Z., Liu J., Settling characteristics analysis of coal slime water based on original hardness, Journal of China Coal Society, 39, 4, pp. 757-763, (2014)
  • [4] Xu Z., Liu J., Choung J.W., Et al., Electrokinetic study of clay interactions with coal in flotation, International Journal of Mineral Processing, 68, 1-4, pp. 183-196, (2003)
  • [5] Zhang Z., Liu J., Zou W., Et al., Effect of water hardness on coal flotation, Journal of China University of Mining & Technology, 40, 4, pp. 612-615, (2011)
  • [6] Bi M., Wang H., Yu P., Study on the effect of slime solution chemical circumstance on flocculation, Clean Coal Technology, 15, 3, pp. 24-26, (2009)
  • [7] Zhang M., Liu J., Wang Y., Effects of water hardness on the dispersion of fine coal and kaolinite in coal slurry, Journal of China Coal Society, 33, 9, pp. 1058-1062, (2008)
  • [8] Wang H., Coal slurry water treatment method based on hydration swelling control of montmorillonite, Coal Engineering, 11, pp. 108-110, (2013)
  • [9] Fan H., Wu P., Li P., Et al., Study on identification of dispersive clay soils, Chinese Journal of Geotechnical Engineering, 27, 11, pp. 1310-1316, (2005)
  • [10] Fan H., Gao M., Li P., Et al., Experimental study on clay dispersibility, Journal of Chang'an University (Natural Science Edition), 27, 2, pp. 76-80, (2007)