Synthesis, Structure and Magnetic Properties of the Sandwich-type Tungstoarsenates Containing Tetrametallic Cluster [M4(H2O)2(AsW9O34) 2]10-(M=CuII, CoII, MnII, NiII, ZnII)

被引：0

作者：

Bi, Li-Hua

Huang, Ru-Dan

Peng, Jun

Wang, En-Bo

机构：

[1] College of Chemistry, Northeast Normal University, Changchun 130024, China

[2] College of Chemistry, Jilin University, Changchun 130025, China

来源：

Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities | 2002年 / 23卷 / 05期

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摘要：

The compounds [M4(H2O)2(AsW9O34) 2]10-(M=CuII, CoII, MnII, NiII, ZnII) were synthesized and characterized by IR, UV, elemental analysis and magnetic measurements. These compounds are isostructural to the P derivatives and comprise a rhomb-like M4O16 group encapsulated between two fragments of the trivacant Keggin polyanion [AsW9O34]9-. The crystal structures of the MnII and CuII derivatives were compared with that of the P derivatives. The MnII derivative exhibits antiferromagnetic Mn - Mn exchange interactions and S=0 ground state.

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