Third-order nonlinear optical properties of Sm2O3 activated cadmium alkali borate glasses

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作者
Hivrekar, Mahesh M. [1 ,13 ]
Jagannath, G. [2 ]
Pramod, A.G. [3 ]
Aloraini, Dalal Abdullah [4 ]
Almuqrin, Aljawhara H. [4 ]
Sayyed, M.I. [5 ,6 ]
Keshavamurthy, K. [7 ]
Hegde, Vinod [8 ]
Sathish, K.N. [9 ]
Mahaboob Pasha, U. [10 ]
Venugopal Rao, S. [11 ]
Yasmin, Sabina [12 ]
Jadhav, K.M. [1 ]
机构
[1] Department of Physics, Dr. Babasaheb Ambedkar Marathwada University, Maharashtra, Aurangabad,431004, India
[2] Department of Post-Graduate Studies and Research in Physics, The National College, Jayanagar, Karnataka, Bengaluru,560070, India
[3] Department of Physics, Bangalore University, Karnataka, Bengaluru,560056, India
[4] Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh,11671, Saudi Arabia
[5] Department of Physics, Faculty of Science, Isra University, Amman, Jordan
[6] Department of Nuclear Medicine Research, Institute for Research and Medical Consultations (IRMC), Imam Abdulrahman bin Faisal University (IAU), P.O. Box 1982, Dammam,31441, Saudi Arabia
[7] Department of Physics, Vivekananda Institute of Technology, Bangalore,560074, India
[8] Department of Physics, Acharya Institute of Graduation Studies, Karnataka, Bengaluru,560107, India
[9] Govt. First Grade College, Karnataka, Chickaballapur,562101, India
[10] Department of Physics, Presidency University, Karnataka, Bangalore,560064, India
[11] Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Telangana, Hyderabad,500046, India
[12] Department of Physics, Chittagong University of Engineering and Technology, Chattogram, Bangladesh
[13] Department of Physics, Gramin Technical & Management Campus, Vishnupuri, Maharashtra, Nanded,431606, India
关键词
Cadmium compounds - Fourier transform infrared spectroscopy - Absorption spectroscopy - Nonlinear optics - Light absorption - Refractive index - Infrared devices - Rare earths - Samarium compounds - Two photon processes;
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摘要
Efficacy of tri‒valent samarium ions concentration on the optical and third‒order nonlinear optical (NLO) properties of multicomponent cadmium alkali borate‒based glasses prepared by standard melting‒quenching method has been investigated in this work. The optical properties of cadmium alkali borate glass activated by rare-earth oxide (i.e., Sm2O3) were carried out by using UV–Visible absorption spectroscopy at room temperature. Optical absorption peaks were obtained around 402 nm, 1076 nm, and 1078 nm wavelength. The Fourier transform infrared spectroscopy results revealed the existence of distinct borate units, in the structure of glasses used in the investigation. Z‒scan experiments in the near‒infrared (NIR) spectral regions utilizing the femtosecond (fs) laser pulses were used in order to evaluate the NLO parameters. The two‒photon absorption coefficient and the index of nonlinear refraction values improved significantly for 2 mol% of Sm2O3. This endorses 2 mol% of Sm2O3 encompassed glasses are beneficial for constructing the NLO devices assigned to perform in the NIR region. © 2022 Elsevier B.V.
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