Polyurethanes based on crown ether derivatives: Study of spectral effects

被引:0
|
作者
Savel'ev, Yu.V. [1 ]
Khranovskij, V.A. [1 ]
Akhranovich, E.R. [1 ]
机构
[1] Inst. of Macromolecular Chemistry, NAS of Ukraine, Khar'kovskoe sh. 48, Kiev, 02160, Ukraine
关键词
Birefringence - Crown ethers - Deformation - Infrared spectroscopy - Light polarization - Reflection;
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学科分类号
摘要
The structure of new polyurethanes based on (macro)heterocyclic compounds and the relation between the inversion of IR dichroism of polyurethanes and the orientational phenomena and the mechanism of deformation of polyurethanes differing in the level of supramolecular organization were studied. The comparative examination of transmission IR spectra and multiple attenuated total reflectance IR spectra combined with the results of polarization measurements under deformation of film samples provides evidence that the studied polymers feature different supramolecular organizations.
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页码:2236 / 2240
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