Thermodynamic modelling of crystal nucleation from liquid and amorphous alloys

被引:0
|
作者
Bosco, E. [1 ]
Baricco, M. [1 ]
机构
[1] Dipartimento di Chimica, INFM, Università di Torino, Torino, Italy
来源
Metallurgia Italiana | 2001年 / 93卷 / 11-12期
关键词
Amorphous alloys - Crystallization - Glass transition - Intermetallics - Metallic glass - Nanostructured materials - Nucleation - Solid solutions - Thermodynamic stability;
D O I
暂无
中图分类号
学科分类号
摘要
The thermodynamics of primary crystal nucleation from liquid and amorphous alloys was studied. The maximum driving force determined the composition of the nucleus, which could be found with the parallel tangents construction. The thermodynamic properties of intermetallic compounds were also considered. It was found that the two crystalline phase showed comparable driving forces for the nucleation from the amorphous phase, due to the stabilization of liquid phase at high undercooling.
引用
收藏
页码:45 / 51
相关论文
共 50 条
  • [1] Driving forces for crystal nucleation in Fe-B liquid and amorphous alloys
    Palumbo, M
    Cacciamani, G
    Bosco, E
    Baricco, M
    INTERMETALLICS, 2003, 11 (11-12) : 1293 - 1299
  • [2] Thermodynamic and kinetic modelling of primary crystallisation in amorphous alloys
    Baricco, M
    Palumbo, M
    ISMANAM 2003: METASTABLE, MECHANICALLY ALLOYED AND NANOCRYSTALLINE MATERIALS, 2004, 20-21 : 415 - 424
  • [3] On thermodynamic properties and atomic structure of amorphous and liquid alloys
    Il'inskii, A
    Kaban, I
    Koval, Y
    Hoyer, W
    Slyusarenko, S
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2004, 345 : 251 - 255
  • [4] ACTIVATION-ENERGIES FOR CRYSTAL NUCLEATION AND GROWTH IN AMORPHOUS-ALLOYS
    LU, K
    WANG, JT
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1991, 133 : 500 - 503
  • [5] Driving force for the nucleation from supercooled liquid and thermodynamic analysis of glass forming ability for binary alloys
    Wang Na
    Li Changrong
    Du Zhenmin
    ACTA METALLURGICA SINICA, 2008, 44 (09) : 1111 - 1115
  • [6] A thermodynamic approach to homogeneous nucleation via fluctuations of concentration in binary liquid alloys
    Cini, E
    Vinet, B
    Desré, PJ
    PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 2000, 80 (04): : 955 - 966
  • [7] Nucleation of shear bands in amorphous alloys
    Perepezko, John H.
    Imhoff, Seth D.
    Chen, Ming-Wei
    Wang, Jun-Qiang
    Gonzalez, Sergio
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2014, 111 (11) : 3938 - 3942
  • [8] THERMODYNAMIC CONDITIONS FOR NUCLEATION OF A SUPERSATURATED SOLID-SOLUTIONS OR AN AMORPHOUS PHASE IN LIQUID ALLOY
    GRESSIN, P
    EUSTATHOPOULOS, N
    DESRE, P
    JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1982, 79 (06) : 545 - 548
  • [9] THERMODYNAMIC ANALYSIS OF CONCENTRATION FLUCTUATIONS AND HOMOGENEOUS NUCLEATION OF CRYSTAL IN UNDERCOOLED LIQUID BINARY-ALLOYS - APPLICATION TO GLASS FORMING ABILITY
    DESRE, P
    JOURNAL OF MATERIALS SCIENCE, 1987, 22 (01) : 57 - 62
  • [10] IN-SITU ANALYSIS OF IRRADIATION-INDUCED CRYSTAL NUCLEATION IN AMORPHOUS-SILICON - A MICROSCOPE FOR THERMODYNAMIC PROCESSES IN NUCLEATION
    SHIN, JH
    ATWATER, HA
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1993, 80-1 : 973 - 977