Preparation and antibacterial and dyeing properties of chitosan grafted antibacterial viscose fiber

被引:0
|
作者
Yao P. [1 ]
Jiang W. [1 ]
Wang J. [1 ]
Huang J. [2 ]
Zhou X. [1 ]
机构
[1] College of Chemistry and Chemical Engineering, Chongqing University, Chongqing
[2] Huimei Thread Industry Co., Ltd., Yibin, 644000, Sichuan
来源
关键词
Antibacterial property; Chitosan; Chitosan grafted antibacterial fiber; Dyeing property; Synthetic process; Viscose fiber;
D O I
10.13475/j.fzxb.20170607905
中图分类号
学科分类号
摘要
In order to synthesize a new type of antibacterial fiber, chitosan grafted antibacterial viscose fiber was prepared using viscose fiber as raw material, chitosan as polynuclear antibacterial fragment and epichlorohydrin as cross linking agent. The process was optimized, and the structure, bacterial resistance and dyeing property of the fiber were characterized. The results show that the optimum process conditions are the mole ratio of chitosan to epichlorohydrin of 1:0.3, the mass ratio of fiber to chitosan of 1:0.8, the temperature of 100℃, the reaction time of 5 h. 2.0% of chitosan is grafted to surface of the fiber under the conditions, and the grafted thickness of chitosan is up to 0.495 μm. The fiber has inhibition rate of Staphylococcus aureus, Escherichia coli, klebsiella pneumonia and Candida albicans is up to 90%, 88%, 91% and 99%, respectively. Owing to the grafting of chitosan, the dyeing fastness and the color fastness of anionic dye are significantly improved, but the dyeing property of cationic dyes are reduced. Copyright No content may be reproduced or abridged without authorization.
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页码:9 / 13
页数:4
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  • [1] Hao W., Yan K., Chen Y., Et al., Chitosan and butane tetracylic acid are antibacterial/anti-wrinkle of cotton fabric, Journal of Textile Research, 37, 6, pp. 95-100, (2016)
  • [2] Eisayed A.A., Dorgharm S.M., Kantouch A., Application of reactive salicylanilide to viscose fabrics as antibacterial and antifungus finishing, International Journal of Biological Macromolecules, 50, 1, pp. 273-276, (2012)
  • [3] Liu L., Chen Y., The development of knitting sport leisure fabrics with aloe viscose antibacterial fiber, Shanghai Textile Science & Technology, 44, 4, pp. 33-47, (2016)
  • [4] Xu J., Researches on the properties of chitosan/viscose antibacterial fiber, Shanghai Textile Sci-ence & Technology, 38, 7, pp. 55-61, (2010)
  • [5] Rehan M., Mowafi S., Aiy S.A., Et al., Microwave-heating for in-situ Ag NPs preparation into viscose fibers, European Polymer Journal, 86, pp. 68-84, (2017)
  • [6] Ibrahim N.A., Eid B.M., Abdel-Aziz M.S., Effect of plasma superficial treatments on antibacterial functionalization and coloration of cellulosic fabrics, Applied Surface Science, 392, pp. 1126-1133, (2017)
  • [7] Elgabry L.K., Allam O.G., Hakeim O.A., Surface functionalization of viscose and polyester fabrics toward antibacterial and coloration properties, Carbohydrate Polymers, 92, 1, pp. 353-359, (2013)
  • [8] Emam H.E., Mowafi S., Mashaly H.M., Et al., Production of antibacterial colored viscose fibers using in situ prepared spherical Ag nanoparticles, Carbohydrate Polymers, 110, 38, pp. 148-155, (2014)
  • [9] Xu Y., Du Z., Liu X., Structure and performance of chitosan imide modified cotton fiber, Journal of Textile Research, 33, 9, pp. 35-39, (2012)
  • [10] Wang X., Lin J., Chen S., Research on antibacterial properties of the viscose fiber with quaternary ammonium salts, Materials Research and Application, 6, 4, pp. 246-250, (2012)