Development of visible-light-driven TiO2 and SrTiO3 photocatalysts doped with metal cations for H2 or O2 evolution

被引:12
|
作者
Niishiro R. [1 ]
Kudo A. [1 ]
机构
[1] Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Shinjuku-ku, Tokyo 162-8601
关键词
Codoping; Doping; Hydrogen evolution; Oxygen evolution; Photocatalyst; Visible-light response; Water splitting;
D O I
10.4028/www.scientific.net/SSP.162.29
中图分类号
学科分类号
摘要
This review paper represents photocatalytic properties of metal cation-doped TiO2 (rutile) and SrTiO3 photocatalysts for O2 evolution from an aqueous silver nitrate solution and H 2 evolution from an aqueous methanol solution under visible light irradiation. Photocatalytic activities for the O2 evolution of Cr/Sb and Rh/Sb-codoped TiO2 are strongly dependent on the codoping ratio and the amount of doped chromium and rhodium. The codopant controls the oxidation number of doped chromium and rhodium. Rh-doped SrTiO3 in which the doped Rh species possesses a reversible redox property is active for the H2 evolution reaction under visible light irradiation. Overall water splitting under visible light irradiation proceeds with Z-scheme photocatalyst systems consisting of the Rh-doped SrTiO3 as a H 2 evolution photocatalyst combined with BiVO4 as an O 2 evolution photocatalyst and an Fe3+/Fe2+ electron mediator. © (2010) Trans Tech Publications.
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页码:29 / 40
页数:11
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