Catalytic conversion of CO2 into high value-added hydrocarbons over tandem catalyst

被引：10
|
作者：
Wang X.-X. [1 ]
Duan Y.-H. [2 ]
Zhang J.-F. [1 ]
Tan Y.-S. [1 ]
机构：
[1] State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan
[2] China Petroleum and Chemical Industry Federation, Beijing
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2022年 / 50卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Active sites; Catalytic conversion; CO[!sub]2[!/sub] hydrogenation; High value-added hydrocarbons; Tandem catalysis;
D O I：
10.1016/S1872-5813(21)60181-0
中图分类号：
学科分类号：
摘要：
The conversion of CO2, an abundant carbon resource, into high value-added chemicals or liquid fuels is an attractive way to mitigate carbon emissions, which is also a sustainable approach for the cyclic utilization of carbon resources. However, the selective activation and controllable conversion of CO2 is challenging because of the inertness of CO2 and high C-C coupling barrier. In recent years, some obvious breakthroughs on CO2 hydrogenation to high value-added chemicals or liquid fuels have been made by construction of a tandem catalytic system. For the tandem catalysis, the matching of Fe-based catalyst or metal oxides and zeolites, the assembly between the two active sites, the pore structure and acidity of the zeolites, as well as the reaction conditions and atmosphere all have important effects on the product distribution. Herein, the critical factors affecting the CO2 activation and conversion and the formation of the target products, as well as the stability over the tandem catalysts are summarized. Finally, an outlook is provided. © 2022, Science Press. All right reserved.
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页码：538 / 563
页数：25
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