Pollution Characteristics and Sources of Water-soluble Ions in PM2.5 in Zhengzhou City

被引：0

作者：

Zhang J.-M. ^{[1
]}

Chen S.-L. ^{[1
]}

Wang Q.-H. ^{[1
]}

Yao S. ^{[1
]}

Yang S.-S. ^{[1
]}

机构：

[1] School of Energy & Environment, Zhongyuan University of Technology, Zhengzhou

来源：

Huanjing Kexue/Environmental Science | 2023年 / 44卷 / 02期

关键词：

conversion ratio; potential source regions; seasonal variation; source apportionment; water-soluble inorganic ions;

D O I：

10.13227/j.hjkx.202112312

中图分类号：

学科分类号：

摘要：

In order to explore the pollution characteristics, seasonal variations, and sources of water-soluble inorganic ions (WSIIs) in PM2. 5 in Zhengzhou, PM2. 5 samples were seasonally collected from December 2020 to October 2021; then, combining gaseous pollutants (SO2 , NO2 , and O3 ) and meteorological parameters (temperature and relative humidity), nine WSIIs (NO3- , NH4+ , SO24- , Ca2 + , K + , Na + , Mg2 + , F - , and Cl - ) were analyzed. The results showed that the annual average concentration of the total water-soluble ions (TWSIIs) was (39. 34 ±21. 56) μg.m -3 for the four seasons, showing obvious seasonal variations with the maximum value in winter and the minimum value in summer. Annual PM2. 5 was slightly alkaline in Zhengzhou, and NH4+ most likely existed in the form of NH4 NO3 and (NH4 )2 SO4 . The average sulfur oxidation ratio (SOR) and nitrogen oxidation ratio (NOR) were 0. 35 and 0. 19, respectively, indicating that SO24- and NO3- mainly derived from secondary formation. The main potential source regions of WSIIs obtained by the concentration weight trajectory (CWT) model showed temporal and spatial variations. The significant sources of WSIIs based on principal component analysis (PCA) were dust, secondary generation, combustion, and industrial activities, which were obviously influenced by wind direction and speed in Zhengzhou. © 2023 Science Press. All rights reserved.

引用

页码：602 / 610

页数：8

共 32 条

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