Carbon electrodes modified with water-soluble charged polymer binder for enhanced capacitive deionization performance

被引:0
|
作者
Wang G. [1 ,2 ]
Che X. [2 ]
Wang S. [1 ]
Qiu J. [2 ]
机构
[1] School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan
[2] State Key Laboratory of Fine Chemicals, Liaoning Key Laboratory for Energy Materials and Chemical Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian
来源
Huagong Xuebao/CIESC Journal | 2022年 / 73卷 / 04期
关键词
Activated carbon; Binder; Capacitive deionization; Surface modification;
D O I
10.11949/0438-1157.20211793
中图分类号
学科分类号
摘要
Capacitive deionization (CDI) is a new desalination technology based on the principle of electrosorption, which has the advantages of low cost, no secondary pollution, and low energy consumption. The hydrophilic binders carboxymethyl cellulose sodium (CMC), polyvinyl alcohol (PVA) and sulfonated carboxymethyl cellulose sodium (SCMC), quaternized polyvinyl alcohol (QPVA) were used to prepare the activated carbon electrodes, which further enhanced the hydrophilicity and ion selectivity of activated carbon (AC) electrodes. The hydrophilic charged polymer binder can effectively inhibit the anodic oxidation reaction and enhance the driving force of ion adsorption by virtue of its own charge. In 500 mg/L NaCl salt solution at 1.2/0 V, AC-CMC//AC-PVA and AC-SCMC//AC-QPVA can obtain 14.58 and 17.39 mg/g of desalination, respectively, And after 100 cycles at 0.8/0 V, the retention rates of desalination were 65.48% and 80.53%, respectively. © 2022, Editorial Board of CIESC Journal. All right reserved.
引用
收藏
页码:1763 / 1771
页数:8
相关论文
共 35 条
  • [1] Ou R, Zhang H, Truong V X, Et al., A sunlight-responsive metal-organic framework system for sustainable water desalination, Nature Sustainability, 3, 12, pp. 1052-1058, (2020)
  • [2] Gamaethiralalage J G, Singh K, Sahin S, Et al., Recent advances in ion selectivity with capacitive deionization, Energy & Environmental Science, 14, 3, pp. 1095-1120, (2021)
  • [3] Liu Y, Wang K, Xu X T, Et al., Recent advances in faradic electrochemical deionization: system architectures versus electrode materials, ACS Nano, 15, 9, pp. 13924-13942, (2021)
  • [4] Li Q, Zheng Y, Xiao D J, Et al., Faradaic electrodes open a new era for capacitive deionization, Advanced Science, 7, 22, (2020)
  • [5] Nam D H, Lumley M A, Choi K S., Electrochemical redox cells capable of desalination and energy storage: addressing challenges of the water-energy nexus, ACS Energy Letters, 6, 3, pp. 1034-1044, (2021)
  • [6] Zhang P H, Li J H, Chan-Park M B., Hierarchical porous carbon for high-performance capacitive desalination of brackish water, ACS Sustainable Chemistry & Engineering, 8, 25, pp. 9291-9300, (2020)
  • [7] Liu M Q, Xu M, Xue Y F, Et al., Efficient capacitive deionization using natural basswood-derived, freestanding, hierarchically porous carbon electrodes, ACS Applied Materials & Interfaces, 10, 37, pp. 31260-31270, (2018)
  • [8] Wang G, Zhang Y Q, Wang S Y, Et al., Boron-nitride-carbon nanosheet/graphene composites generated by covalent cross-linking which have an excellent capacitive deionization performance, New Carbon Materials, 35, 4, pp. 384-393, (2020)
  • [9] Kalfa A, Shapira B, Shopin A, Et al., Capacitive deionization for wastewater treatment: opportunities and challenges, Chemosphere, 241, (2020)
  • [10] Gong X Y, Luo W X, Guo N N, Et al., Carbon nanofiber@ZIF-8 derived carbon nanosheet composites with a core-shell structure boosting capacitive deionization performance, Journal of Materials Chemistry A, 9, 34, pp. 18604-18613, (2021)