Methods for measuring vaporization enthalpies of ionic liquids

被引：0
|
作者：
Song S. [1 ]
Yao J. [1 ]
Li H. [1 ,2 ]
机构：
[1] Department of Chemistry, Zhejiang University, Hangzhou, 310027, Zhejiang
[2] State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, Zhejiang
来源：
Huagong Xuebao/CIESC Journal | 2020年 / 71卷 / 01期
关键词：
Enthalpy; Ionic liquids; Measurement; Thermodynamics; Vaporization;
D O I：
10.11949/0438-1157.20191240
中图分类号：
学科分类号：
摘要：
Due to their characteristics, such as low vapor pressure, low volatilization, strong electrical conductivity, stable chemical properties, recyclability and so on, ionic liquids (ILs) can replace organic solvents as a new environmentally friendly solvent, can be used as a catalyst to catalyze chemical reactions, can participate in electrochemical reactions as electrolyte solutions, can make new batteries and so on. It is generally believed that ILs are not volatile and their vaporization enthalpies cannot be measured. However, in recent years, the related research results of ILs have been reviewed, and it has been found that researchers have successively proposed many methods for obtaining vaporization enthalpies of ILs. We will systematically introduce these methods, expounding their principles, and laying a solid foundation for future research. © All Right Reserved.
引用
收藏
页码：26 / 33
页数：7
相关论文
共 73 条
  • [1] Welton T., Room-temperature ionic liquids. solvents for synthesis and catalysis, Chemical Reviews, 99, 8, pp. 2071-2084, (1999)
  • [2] Galinski M., Lewandowski A., Stepniak I., Ionic liquids as electrolytes, Electrochimica Acta, 51, 26, pp. 5567-5580, (2006)
  • [3] Hallett J.P., Welton T., Room-temperature ionic liquids: solvents for synthesis and catalysis, Chemical Reviews, 111, 5, pp. 3508-3576, (2011)
  • [4] Zhang P.F., Gong Y.T., Lv Y.Q., Et al., Ionic liquids with metal chelate anions, Chemical Communications, 48, 17, pp. 2334-2336, (2012)
  • [5] Itoh T., Han S., Matsushita Y., Et al., Enhanced enantioselectivity and remarkable acceleration on the lipase-catalyzed transesterification using novel ionic liquids, Green Chemistry, 6, 9, pp. 437-439, (2004)
  • [6] Di J., Xia J.X., Yin S., Et al., One-pot solvothermal synthesis of Cu-modified BiOCl via a Cu-containing ionic liquid and its visible-light photocatalytic properties, RSC Advances, 4, 27, pp. 14281-14290, (2014)
  • [7] Huang C.P., Liu Z.C., Xu C.M., Et al., Effects of additives on the properties of chloroaluminate ionic liquids catalyst for alkylation of isobutane and butane, Applied Catalysis A: General, 277, 1-2, pp. 41-43, (2004)
  • [8] Yin S., Di J., Li M., Sun Y.L., Et al., Ionic liquid-assisted synthesis and improved photocatalytic activity of p-n junction g-C<sub>3</sub>N<sub>4</sub>/BiOCl, Journal of Materials Science, 51, 10, pp. 4769-4777, (2016)
  • [9] Chiappe C., Pieraccini D., Ionic liquids: solvent properties and organic reactivity, Journal of Physical Organic Chemistry, 18, 4, pp. 275-297, (2005)
  • [10] Park J.W., Yamauchi K., Takashima E., Et al., Solvent effect of room temperature ionic liquids on electrochemical reactions in lithium-sulfur batteries, The Journal of Physical Chemistry C, 117, 9, pp. 4431-4440, (2013)
12345678