Oxidation Resistance and Microwave Absorption of FeCo@Nano-SiO2

被引:0
|
作者
Li J. [1 ]
Zhu Y. [1 ]
Li X. [1 ]
Chen P. [1 ]
Zhu B. [1 ]
机构
[1] The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan
关键词
Effective absorption bandwidth; Electromagnetic wave absorption; Iron-cobalt alloy@nano-silicon dioxide; Oxidation resistance;
D O I
10.14062/j.issn.0454-5648.20200651
中图分类号
学科分类号
摘要
FeCo@nano-SiO2 was prepared via a modified Stöber method using tetraethyl orthosilicate using FeCo as raw materials. The results show that the powder has a uniform core-shell structure. The reflection loss (RL) of FeCo@nano-SiO2 reaches -36.1 dB with the thickness of 2.6 mm, and the effective absorption bandwidth with RL< -10 dB is 3.2 GHz when the content of SiO2 is 35% (in mass fraction). The mass of FeCo@nano-SiO2 only increases 2% from room temperature to 800 °C, and the optimum oxidation resistance can be obtained at the content of SiO2 of 65%. The SiO2 shell optimizes the impedance matching of FeCo, further facilitating the electromagnetic wave absorption, and prevents the contact between FeCo and oxygen at a high temperature, thus improving the oxidation resistance. © 2021, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码:1135 / 1142
页数:7
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共 21 条
  • [1] YANG F, CHEN H, LIU D, Et al., The microstructure and magnetic properties of FeCo@SiO<sub>2</sub> core-shell nanoparticles synthesized by using a solution method, J Alloy Compd, 728, pp. 1153-1156, (2017)
  • [2] WEI Y, YUE J, TANG X Z, Et al., Enhanced magnetic and microwave absorption properties of FeCo-SiO<sub>2</sub> nanogranular film functionalized carbon fibers fabricated with the radio frequency magnetron method, Appl Surf Sci, 428, pp. 296-303, (2018)
  • [3] LIANG C, LIU C, WANG H, Et al., SiC-Fe<sub>3</sub>O<sub>4</sub> dielectric-magnetic hybrid nanowires: controllable fabrication, characterization and electromagnetic wave absorption, J Mater Chem A, 2, 39, pp. 16397-16402, (2014)
  • [4] CHEN N, JIANG J T, XU C Y, Et al., Co<sub>7</sub>Fe<sub>3</sub> and Co<sub>7</sub>Fe<sub>3</sub>@SiO<sub>2</sub> nanospheres with tunable diameters for high-performance electromagnetic wave absorption, ACS Appl Mater Interfaces, 9, 26, pp. 21933-21941, (2017)
  • [5] TANG N J, ZHONG W, JIANG H Y, Et al., Complex permeability of FeNi<sub>3</sub>/SiO<sub>2</sub> core-shell nanoparticles, Solid State Commun, 132, 2, pp. 71-74, (2004)
  • [6] WANG Y, ZHANG W, LUO C, Et al., Superparamagnetic FeCo@SnO<sub>2</sub> nanoparticles on graphene-polyaniline: Synthesis and enhanced electromagnetic wave absorption properties, Ceram Int, 42, 10, pp. 12496-12502, (2016)
  • [7] CHENG Y, GUO Y H, ZHANG Z Y, Et al., Achieving the broader frequency electromagnetic absorber by development of magnetic core-shell composite with tunable shell/core sizes, Appl Surf Sci, 434, pp. 763-770, (2018)
  • [8] WANG J Q, CUI Y H, WU F, Et al., Core-shell structured Fe/Fe<sub>3</sub>O<sub>4</sub>@TCNFs@TiO<sub>2</sub> magnetic hybrid nanofibers: Preparation and electromagnetic parameters regulation for enhanced microwave absorption, Carbon, 165, pp. 275-285, (2020)
  • [9] DING L, HUANG Y, LIU X, Et al., Broadband and multilayer core-shell FeCo@C@mSiO<sub>2</sub> nanoparticles for microwave absorption, J Alloy Compd, 812, (2020)
  • [10] WANG Z, ANG J, ZHANG B, Et al., FeCo/FeCoNi/N-doped carbon nanotubes grafted polyhedron-derived hybrid fibers as bifunctional oxygen electrocatalysts for durable rechargeable zinc-air battery, Appl Catal B-Environ, 254, pp. 26-36, (2019)