NaClO/Fe2+ Coagulation to Improve Dewatering Performance of Algae-containing Sludge and Mechanism Investigation

被引:0
|
作者
Tang Y. [1 ,2 ]
Wu M. [1 ,2 ]
Sun T. [1 ,2 ]
Wang M. [3 ]
Zhang M. [3 ]
Wang Y. [3 ]
机构
[1] School of Environmental Science and Engineering, Tongji University, Shanghai
[2] State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai
[3] Wuxi Public Utilities Environment Testing Research Institute Co. Ltd., Wuxi
来源
关键词
Algae-containing sludge; Algae-laden water; Dewatering; Enhanced coagulation;
D O I
10.11908/j.issn.0253-374x.21250
中图分类号
学科分类号
摘要
Sodium hypochlorite/ferrous salt coagulation can efficiently improve the dewatering performance and effect of algae-containing sludge. When the NaClO dosage was 1.5~2.0 mg·L-1, the dewatering performance reached the best. The oxidizing property of excessive NaClO damaged the integrity of algae cells. The overflow of intracellular substances hindered the release of water between cells, leading to the decrease of dewatering performance. Under the oxidation effect of NaClO, Fe2+ was transformed into Fe3+ in situ and further formed Fe(OH)3, which enhanced the coagulation effect. The hydrophilic components of extracellular polymeric substances such as protein and polysaccharides were partially degraded by NaClO, which was beneficial to the release of water between cells. Hence, the dewatering performance was improved. In addition, the removal rate of dissolved organic matter by NaClO/Fe2+ coagulation increased from 74% to 90%, and the content of humus macromolecules and aromatic compounds was also reduced, improving the purification effect of algae-laden water. © 2021, Editorial Department of Journal of Tongji University. All right reserved.
引用
收藏
页码:1226 / 1233
页数:7
相关论文
共 19 条
  • [1] CARMICHAEL W W, BOYER G L., Health impacts from cyanobacteria harmful algae blooms: implications for the North American Great Lakes, Harmful Algae, 54, (2016)
  • [2] ZHU X, HU M M., Control and prevention of cyanobacteria outbreak in freshwater lakes in China, (2014)
  • [3] LIANG J, ZHANG S, HUANG J, Et al., Comprehensive insights into the inorganic coagulants on sludge dewatering: comparing aluminium and iron salts, Journal of Chemical Technology and Biotechnology, 94, 5, (2019)
  • [4] DRIKAS M, CHOW C W K, HOUSE J, Et al., Using coagulation, flocculation, and settling to remove toxic cyanobacteria, Journal American Water Works Association, 93, 2, (2001)
  • [5] LI G M, JIN Y Y, LI H, Et al., Study on effects of inorganic conditioner on sludge reuse as buliding materials, China Water & Wastewater, 13, (2006)
  • [6] CHEN M Z, MO J N, LU W, Et al., Discussion on the high algae content water treatment, Water & Wastewater Engineering, 45, 7, (2009)
  • [7] MA M, LIU R, LIU H, Et al., Chlorination of microcystis aeruginosa suspension: cell lysis, toxin release and degradation, J Hazard Mater, 217, (2012)
  • [8] WEI H, TANG Y, SHOEIB T, Et al., Evaluating the effects of the preoxidation of H<sub>2</sub>O<sub>2</sub>, NaClO, and KMnO<sub>4</sub> and reflocculation on the dewaterability of sewage sludge, Chemosphere, 234, (2019)
  • [9] MA M, LIU R, LIU H, Et al., Effect of moderate pre-oxidation on the removal of Microcystis aeruginosa by KMnO<sub>4</sub>-Fe(II) process: significance of the in-situ formed Fe(III), Water Research, 46, 1, (2012)
  • [10] XU Y, WANG G, YANG W, Et al., Dynamics of the water bloom-forming microcystis and its relationship with physicochemical factors in Lake Xuanwu (China), Environmental Science and Pollution Research, 17, 9, (2010)