Stabilization of sp-Hybridized Nitrogen Cation by Lewis Acid-Base Complex Formation with Intramolecular Iodine

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作者
Fujino, Tomohiro [1 ]
Hyodo, Tadashi [2 ]
Otani, Yuko [1 ]
Yamaguchi, Kentaro [2 ]
Ohwada, Tomohiko [1 ]
机构
[1] Department of Organic and Medicinal Chemistry, Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Tokyo, Bunkyo-ku,113-0033, Japan
[2] Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, 1314-1 Shido, Kagawa, Sanuki,769-2193, Japan
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Engineering Village;
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e202303393
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摘要
Acid-base complex - Hypervalent iodine - Hypervalent iodine(III) - Lewis Acid - Lewis acid-base - Nitrogen lewis acid - N−I bond - Sp-hybridized nitrogen cation - Trifluoroacetates - Α-hydroxylation
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