Preparation and properties of BaSO4/TPU nanocomposites

被引:0
|
作者
Kong X. [1 ]
Gong J. [1 ]
Fan B. [2 ]
Ma J. [1 ]
机构
[1] State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai
[2] Shanghai Yongli Belting Company Limited, Shanghai
关键词
BaSO[!sub]4[!/sub; nanocomposites; tensile property; thermoplastic polyurethane; X ray developing properties;
D O I
10.13801/j.cnki.fhclxb.20221012.002
中图分类号
学科分类号
摘要
During the operation of the conveyor belt used in the food industry, the plastic particles on the surface layer may fall off and adhere to the food, resulting in unqualified food quality and a negative impact on human health. Therefore, it is of great importance to research the modification of surface layer materials that can be detected by X-rays. In this study, BaSO4/thermoplastic polyurethane (TPU) nanocomposites were prepared by the melt blending method. The phase morphology, thermal stability, and tensile property of BaSO4/TPU nanocomposites were systematically characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA), hardness, and tensile property tests. In particular, the X ray developing properties of the composites were characterized by X ray fluoroscopy tests. SEM shows that BaSO4/TPU nanocomposites are the best. The tensile strength, elongation at break and work of fracture improve by 10.19%, 30.09% and 31.92% compared to unmodified TPU. The TGA test results show that the high-temperature thermal stability of BaSO4/TPU nanocomposites is improved. In addition, by adding BaSO4, the X ray developing properties of the composites are also improved, thus realizing the application in the surface layer of conveyor belts. © 2023 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
引用
收藏
页码:3892 / 3899
页数:7
相关论文
共 22 条
  • [1] KANBUR Y, TAYFUN U., Investigating mechanical, thermal, and flammability properties of thermoplastic polyurethane/carbon nanotube composites[J], Journal of Thermoplastic Composite Materials, 31, 12, pp. 1661-1675, (2018)
  • [2] WANG W, LIAO X, HE Y, Et al., Thermoplastic polyurethane/polytetrafluoroethylene composite foams with enhanced mechanical properties and anti-shrinkage capability fabricated with supercritical carbon dioxide[J], The Journal of Supercritical Fluids, 163, (2020)
  • [3] KAUSAR A., Polyurethane composite foams in high-performance applications: A review[J], Polymer-Plastics Technology and Engineering, 57, 4, pp. 346-369, (2018)
  • [4] BASHIR A, MAQBOOL M, LV R, Et al., Surface modified boron nitride towards enhanced thermal and mechanical performance of thermoplastic polyurethane composite[J], Composites Part B: Engineering, 218, (2021)
  • [5] HUANG A, PENG X, TURNG L S., In-situ fibrillated polytetrafluoroethylene (PTFE) in thermoplastic polyurethane (TPU) via melt blending: Effect on rheological behavior, mechanical properties, and microcellular foamability[J], Polymer, 134, pp. 263-274, (2018)
  • [6] JUN Y, HABIBPOUR S, HAMIDINEJAD M, Et al., Enhanced electrical and mechanical properties of graphene nano-ribbon/thermoplastic polyurethane composites[J], Carbon, 174, pp. 305-316, (2021)
  • [7] BALA H, FU W, GUO Y, Et al., In situ preparation and surface modification of barium sulfate nanoparticles, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 274, 1-3, pp. 71-76, (2006)
  • [8] YAN Zhiyong, YUAN Menghong, HUANG Suping, Et al., Study on X-ray developing fiber[J], China Synthetic Fiber Industry, 2, pp. 32-34, (2002)
  • [9] LUO C, CHEN G, ZHU K, Et al., Preparation of X-ray developable LDPE/SA-BaSO<sub>4</sub> composites and their thermal and mechanical properties[J], Polymer Composites, 37, 5, pp. 1396-1406, (2016)
  • [10] ROMERO-IBARRA I C, BONILLA-BLANCAS E, SANCHEZSOLIS A, Et al., Influence of X-ray opaque BaSO<sub>4</sub> nanoparticles on the mechanical, thermal and rheological properties of polyoxymethylene nanocomposites, Journal of Polymer Engineering, 32, 4-5, pp. 319-326, (2012)