Solid Polymer Electrolytes Based on Comb-Like Thermoplastic Polyurethane

被引：0
|
作者：
Song Y. [1 ]
Ren N. [1 ]
Cong B. [1 ]
Bao J. [1 ]
Tao C. [1 ]
Xu G. [1 ]
Huang Y. [1 ]
Cheng Q. [1 ]
机构：
[1] School of Chemistry and Chemical Engineering, Anhui University, Anhui Province Engineering Technology Research Center of Water-Borne Polymer Materials, Hefei
来源：
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2019年 / 35卷 / 02期
关键词：
Ionic conductivity; Solid polymer electrolytes; Thermoplastic polyurethane; Trimethylolpropane polyethylene glycol monomethyl ether;
D O I：
10.16865/j.cnki.1000-7555.2019.0038
中图分类号：
学科分类号：
摘要：
A series of comb-like thermoplastic polyurethane (TPU) with trimethylolpropane polyethylene glycol monomethyl ether(Ymer-N120), poly-terephthalic acid-3- methyl-1,5-amyl glycol ester diol(TPA-1000), isophorone diisocyanate and 1,4-butanediol were synthesized. Solid polymer electrolytes (SPEs) were fabricated by adding LiTFSI to TPU with the content of 20%. The influence of the amount of TPA-1000 and Ymer-N120 on properties of the SPEs was discussed. The results show that the relationship between the ionic conductivity of the SPEs and temperature is consistent with the Arrhenius equation. The glass transition temperature and tensile strength decrease with the increase of Ymer-N120 content. The comprehensive properties of electrolyte are obtained when the mass ratio of Ymer-120 and TPA-1000 is 1:2 (SPE4). The tensile strength of SPE4 is 0.88 MPa with the ionic conductivity of 1.07×10-4 S/cm at 80℃. The discharge capacity of the solid-state lithium battery assembled by SPE4 reaches 138 mA•h/g at 0.2 C under 80℃. © 2019, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
引用
收藏
页码：47 / 53
页数：6
相关论文
共 16 条
  • [1] Shim J., Kim L., Kim H.J., Et al., All-solid-state lithium metal battery with solid polymer electrolytes based on polysiloxane crosslinked by modified natural gallic acid, Polymer, 122, pp. 222-231, (2017)
  • [2] Zainab G., Wang X., Yu J., Et al., Electrospun polyacrylonitrile/polyurethane composite nanofibrous separator with electrochemical performance for high power lithium ion batteries, Mater. Chem. Phys., 182, pp. 308-314, (2016)
  • [3] Mustapa S.R., Aung M.M., Ahmad A., Et al., Preparation and characterization of Jatropha oil-based polyurethane as non-aqueous solid polymer electrolyte for electrochemical devices, Electrochim. Acta, 222, pp. 293-302, (2016)
  • [4] Chen H., Wang S.Y., Yu W.J., Et al., KH550 modified waterborne polyurethane-based polymer electrolytes, Chemical Propellants & Polymeric Materials, 13, 6, pp. 76-80, (2015)
  • [5] Zhu C.L., Tao C., Bao J.J., Et al., Study on the preparation and properties of polymer electrolytes based on waterborne polyurethane, China Plastics Industry, 43, 12, pp. 132-136, (2015)
  • [6] Luo W.X., Liu Y.P., Yang S.Y., Et al., Synthesis and conduction mechanism of comb-like polymethacrylate solid polymer electrolytes, Acta Polymerica Sinica, 1, pp. 63-71, (2013)
  • [7] Zhang L.L., Lin Q., Yao J.Y., Et al., Preparation and properties of waterborne polyurethane from melamine resin by crosslinking modification, China Plastics Industry, 11, pp. 54-58, (2016)
  • [8] Liu L., Wu X., Li T., Novel polymer electrolytes based on cationic polyurethane with different alkyl chain length, J. Power Sources, 249, pp. 397-404, (2014)
  • [9] Mustapa S.R., Aung M.M., Ahmad A., Et al., Preparation and characterization of Jatropha oil-based polyurethane as non-aqueous solid polymer electrolyte for electrochemical devices, Electrochim. Acta, 222, pp. 293-302, (2016)
  • [10] Ren N., Song Y., Tao C., Et al., Effect of the soft and hard segment composition on the properties of waterborne polyurethane-based solid polymer electrolyte for lithium ion batteries, J. Solid State Electrochem., 22, pp. 1109-1121, (2018)
12