Microwave-Assisted Treatment of Waste Wood Biomass with Deep Eutectic Solvents

被引:3
|
作者
Colella, Marco [1 ,2 ]
Romanazzi, Giuseppe [1 ]
Petrelli, Valentina [1 ]
Baldassarre, Francesca [2 ,3 ]
Ciccarella, Giuseppe [2 ,3 ]
Catauro, Michelina [4 ]
Mastrorilli, Pietro [1 ]
Dell'Anna, Maria Michela [1 ]
机构
[1] Politecnico di Bari, DICATECh, via Orabona, 4, Bari,70125, Italy
[2] Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali & UdR INSTM, Università del Salento, via Monteroni, Lecce,73100, Italy
[3] Istituto di Nanotecnologia − CNR NANOTEC, Consiglio Nazionale delle Ricerche, Via Monteroni, Lecce,73100, Italy
[4] Dipartimento di Ingegneria, Università degli Studi della Campania, via Roma 29, Aversa,81031, Italy
关键词
Chlorine compounds - Degradation - Eutectics - Hydrogen bonds - Ionic liquids - Lignin - Oxalic acid - Solvents - Wood;
D O I
10.1002/masy.202100284
中图分类号
学科分类号
摘要
Deep eutectic solvents (DESs) are new sustainable and cheap reaction media combining the features of both ionic liquids and organic solvents. They are made up by association of hydrogen-bond donors and hydrogen-bond acceptors, and they can promote the hydrolysis of lignocellulosic bonds. Herein the microwave-assisted treatment of waste wood flours with a DES constituted by choline chloride and oxalic acid to get a cellulosic residue separated from lignin degradation products is reported. The insoluble deposit is characterized by SEM, TGA, DSC, FTIR-ATR, and 1H-13C CP/MAS NMR techniques and can be available for further uses such as nanocellulose production. © 2022 Wiley-VCH GmbH.
引用
收藏
相关论文
共 50 条
  • [1] Microwave-Assisted Treatment of Waste Wood Biomass with Deep Eutectic Solvents (vol 404, 2100284, 2022)
    Colella, Marco
    Romanazzi, Giuseppe
    Petrelli, Valentina
    Baldassarre, Francesca
    Ciccarella, Giuseppe
    Catauro, Michelina
    Mastrorilli, Piero
    Dell'Anna, Maria Michela
    [J]. MACROMOLECULAR SYMPOSIA, 2022, 406 (01)
  • [2] Green Deep Eutectic Solvents for Microwave-Assisted Biomass Delignification and Valorisation
    Grillo, Giorgio
    Calcio Gaudino, Emanuela
    Rosa, Roberto
    Leonelli, Cristina
    Timonina, Ana
    Grygiskis, Saulius
    Tabasso, Silvia
    Cravotto, Giancarlo
    [J]. MOLECULES, 2021, 26 (04):
  • [3] Rapid microwave-assisted biomass delignification and lignin depolymerization in deep eutectic solvents
    Muley, Pranjali D.
    Mobley, Justin K.
    Tong, Xinjie
    Novak, Brian
    Stevens, Joseph
    Moldovan, Dorel
    Shi, Jian
    Boldor, Dorin
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2019, 196 : 1080 - 1088
  • [4] Effective delignification of lignocellulosic biomass by microwave assisted deep eutectic solvents
    Kohli, Kirtika
    Katuwal, Sarmila
    Biswas, Atanu
    Sharma, Brajendra K.
    [J]. BIORESOURCE TECHNOLOGY, 2020, 303
  • [5] Ultrafast fractionation of lignocellulosic biomass by microwave-assisted deep eutectic solvent pretreatment
    Chen, Zhu
    Wan, Caixia
    [J]. BIORESOURCE TECHNOLOGY, 2018, 250 : 532 - 537
  • [6] Pretreatment of waste biomass in deep eutectic solvents: Conductive heating versus microwave heating
    Kumar, Narendra
    Muley, Pranjali D.
    Boldor, Dorin
    Coty, Gary G.
    Lynam, Joan G.
    [J]. INDUSTRIAL CROPS AND PRODUCTS, 2019, 142
  • [7] Microwave-assisted extraction of pectin from orange peel using deep eutectic solvents
    Turan, Ozlem
    Isci, Asli
    Yilmaz, Merve Silanur
    Tolun, Aysu
    Sakiyan, Ozge
    [J]. SUSTAINABLE CHEMISTRY AND PHARMACY, 2024, 37
  • [8] Microwave-Assisted Lignin Extraction-Utilizing Deep Eutectic Solvents to Their Full Potential
    Meindl, Alina
    Petutschnigg, Alexander
    Schnabel, Thomas
    [J]. POLYMERS, 2022, 14 (20)
  • [9] Optimization of softwood pretreatment by microwave-assisted deep eutectic solvents at high solids loading
    Ceaser, Regan
    Rosa, Silvia
    Montane, Daniel
    Constanti, Magda
    Medina, Francesc
    [J]. BIORESOURCE TECHNOLOGY, 2023, 369
  • [10] Microwave-assisted extraction with natural deep eutectic solvents for polyphenol recovery from agrifood waste: Mature for scaling-up?
    Tapia-Quiros, Paulina
    Granados, Merce
    Sentellas, Sonia
    Saurina, Javier
    [J]. SCIENCE OF THE TOTAL ENVIRONMENT, 2024, 912