Research Progress of Mn4+ Activated Typical LED Red Phosphors

被引:0
|
作者
Zhang W. [1 ]
He M.-T. [1 ]
Qiao X.-S. [1 ]
Fan X.-P. [1 ]
机构
[1] State Key Laboratory of Silicon Materials & School of Materials Science and Engineering, Zhejiang University, Hangzhou
来源
基金
中国国家自然科学基金;
关键词
LED; Mn[!sup]4+[!/sup; Photoluminescence; Red phosphors;
D O I
10.37188/CJL.20210148
中图分类号
学科分类号
摘要
Mn4+-doped red phosphors have attracted much attention in the fields of white LED indoor lighting, agricultural plant growth and backlight displaying, due to the advantages of broad-band absorption, narrow-band emission, high color purity and low cost. This work reviews recent progress of Mn4+ activated typical LED red phosphors. First, the crystal field theory of Mn4+ is discussed. Then, the research progress of Mn4+ activated fluorides and aluminates is summarized. Next, how to improve luminescence performance, thermal stability and moisture resistance are discussed theoretically. Finally, the main problems in the development of Mn4+ doped red phosphors are presented and the future trends are prospected. © 2021, Science Press. All right reserved.
引用
收藏
页码:1345 / 1364
页数:19
相关论文
共 140 条
  • [1] SCHUBERT E F, KIM J K., Solid-state light sources getting smart [J], Science, 308, 5726, pp. 1274-1278, (2005)
  • [2] LI J H, YAN J, WEN D W, Et al., Advanced red phosphors for white light-emitting diodes [J], J. Mater. Chem. C, 4, 37, pp. 8611-8623, (2016)
  • [3] ZHANG X J, YU J B, WANG J, Et al., All-inorganic light convertor based on phosphor-in-glass engineering for next-generation modular high-brightness white LEDs/LDs [J], ACS Photonics, 4, 4, pp. 986-995, (2017)
  • [4] CHEN W T, SHEU H S, LIU R S, Et al., Cation-size-mismatch tuning of photoluminescence in oxynitride phosphors [J], J. Am. Chem. Soc, 134, 19, pp. 8022-8025, (2012)
  • [5] ZHANG X J, TSAI Y T, WU S M, Et al., Facile atmospheric pressure synthesis of high thermal stability and narrow-band red-emitting SrLiAl<sub>3</sub>N<sub>4</sub>:Eu<sup>2+</sup> phosphor for high color rendering index white light-emitting diodes [J], ACS Appl. Mater. Interfaces, 8, 30, pp. 19612-19617, (2016)
  • [6] FELDMANN C, JUSTEL T, RONDA C R, Et al., Inorganic luminescent materials:100 years of research and application [J], Adv. Funct. Mater, 13, 7, pp. 511-516, (2003)
  • [7] DAICHO H, IWASAKI T, ENOMOTO K, Et al., A novel phosphor for glareless white light-emitting diodes [J], Nat. Commun, 3, 1, pp. 1132-1, (2012)
  • [8] ZEUNER M, SCHMIDT P J, SCHNICK W., One-pot synthesis of single-source precursors for nanocrystalline LED phosphors M<sub>2</sub>Si<sub>5</sub>N<sub>8</sub>:Eu<sup>2+</sup> (M=Sr, Ba), Chem. Mater, 21, 12, pp. 2467-2473, (2009)
  • [9] XIE R J, HIROSAKI N., Silicon-based oxynitride and nitride phosphors for white LEDs-a review [J], Sci. Technol. Adv. Mater, 8, 7-8, pp. 588-600, (2007)
  • [10] STEIGERWALD D A, BHAT J C, COLLINS D, Et al., Illumination with solid state lighting technology [J], IEEE J. Sel. Top. Quantum Electron, 8, 2, pp. 310-320, (2002)