PREPARATION AND THERMAL PROPERTIES OF HYBRID SHELL PHASE CHANGE MICROCAPSULES

被引:0
|
作者
Wang Z. [1 ]
Luan J. [1 ]
机构
[1] School of Energy and Environment, Shenyang University of Aeronautics and Astronautics, Shenyang
来源
关键词
nanomaterials; phase change heat storage; renewable energy; thermal properties; titanium dioxide;
D O I
10.19912/j.0254-0096.tynxb.2022-0743
中图分类号
学科分类号
摘要
In-situ polymerization was adopted to prepare a structure- stable and leakproof phase change microcapsule,which was composed of paraffin as heat storage core material,titanium dioxide and chitosan as shell and graphene nanoplatelets(GNP)as thermal conductive filler. SEM、FTIR、TGA、DSC and thermal conductivity tester were used to investigate the effect of different core-shell ratio and GNP filling amount on the microstructure ,surface functional groups,thermal stability,phase transformation and thermal conductivity of microcapsules. The results indicated that microcapsules have a compact structure and good leakage resistance. The maximum phase change latent heat of the microcapsules is 134.78 J/g,and the corresponding coating rate is 75.51% . The thermal conductivity of microcapsules increased by 261.5% due to the introduce of GNP. © 2023 Science Press. All rights reserved.
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页码:527 / 531
页数:4
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共 13 条
  • [1] JI X Y,, CHEN J, DANG G Z,, Et al., Preparation of phase change microcapsules with inorganic/polymer hybrid shell through a“two-step”reaction[J], Polymer science,series B, 61, 5, pp. 560-566, (2019)
  • [2] XU C Y, GOU W W,, WANG X M,, Et al., Synthesis of paraffin@PS/reduced graphene oxide microcapsules via Pickering emulsion for multi-protective coatings[J], Colloids and surfaces A:physicochemical and engineering aspects, 613, (2021)
  • [3] EAMES P., Thermal energy storage for low and medium temperature applications using phase change materials—a review[J], Applied energy, 177, pp. 227-238, (2016)
  • [4] SONG J H, MA J S, LI F Y, Et al., Experimental research of the phase-change heat storage materials pentaerythrotol and trimethylolethane[J], Acta energiae solaris sinica, 38, 9, pp. 2498-2504, (2017)
  • [5] LOU L, JIANG Z N,, ZHANG Q P,, Et al., Phase change microcapsules with lead tungstate shell for gamma radiation shielding and thermal energy storage[J], International journal of energy research, 43, 14, pp. 8398-8409, (2019)
  • [6] TAN J M., Properties of form- stable paraffin/silicon dioxide/expanded graphite phase change composites prepared by sol- gel method[J], Applied energy, 92, pp. 456-461, (2012)
  • [7] ZHANG J L,, DING Y,, QU L J,, Et al., Discharge performance of a thermal energy storage unit with paraffin-expanded graphite composite phase change materials[J], Energy storage science and technology, 8, 1, pp. 108-115, (2019)
  • [8] Stearyl alcohol/palm triple pressed acid- graphite nanocomposites as phase change materials[J], Thermochimica acta, 663, pp. 77-84, (2018)
  • [9] WANG T Y,, JIANG Y, HUANG J,, Et al., High thermal conductive paraffin/calcium carbonate phase change microcapsules based composites with different carbon network[J], Applied energy, 218, pp. 184-191, (2018)
  • [10] LIU L Z, Et al., Encapsulation of polar phase change materials via multiemulsification and crosslinking method and its application in building[J], Journal of applied polymer science, 136, 32, pp. 47837-47832, (2019)