State of the art on hydrogen storage of sⅡ clathrate hydrate

被引：0
|
作者：
Yue Z. [1 ,2 ,3 ,4 ,5 ]
Long Z. [1 ,2 ,3 ,4 ]
Zhou X. [1 ,2 ,3 ,4 ]
Zang X. [1 ,2 ,3 ,4 ]
Liang D. [1 ,2 ,3 ,4 ]
机构：
[1] Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangdong, Guangzhou
[2] Key Laboratory of Gas Hydrate, Chinese Academy of Sciences, Guangdong, Guangzhou
[3] Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangdong, Guangzhou
[4] State Key Laboratory of Natural Gas Hydrate, Beijing
[5] Nano Science and Technology Institute, University of Science and Technology of China, Jiangsu, Suzhou
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2023年 / 42卷 / 10期
关键词：
hydrate; hydrogen; hydrogen storage capacity; phase equilibria; sⅡ hydrate promoter;
D O I：
10.16085/j.issn.1000-6613.2022-2053
中图分类号：
学科分类号：
摘要：
As a green energy carrier with wide sources, clean and zero carbon, hydrogen energy is an important way for China to achieve the long-term goals of carbon peak and carbon neutral. Due to its easy flammability, explosion and diffusion, one of the greatest challenges of hydrogen energy development is how to store hydrogen safely, efficiently and economically. As a new form of solid materials, storage of hydrogen in clathrate hydrates is carried out by capturing the hydrogen molecules into the three-dimensional cage structure (such as type Ⅰ, type Ⅱ, type H and semi-clathrate) formed by hydrogen-bonded water molecules with the help of different kinds of promoters. Considering the hydrogen storage density and hydrate formation stability, it is found that sⅡ hydrate promoters have the most promising potential. This paper first summarizes the influence of existing sⅡ hydrate promoters on the thermodynamic conditions of hydrogen hydrate formation, then compares the hydrogen storage capacity and the microscopic crystal structure changes of hydrogen hydrate in different promoter systems, and finally states the current development trend at home and abroad. It will provide theoretical guidance and technical support for the future industrial application of hydrogen hydrate storage. © 2023 Chemical Industry Press. All rights reserved.
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页码：5121 / 5134
页数：13
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