Experimental study on multi-scale pore structure characteristics of tar-rich coal in Yushenfu mining area

被引:0
|
作者
Shen Y. [1 ,2 ]
Wang X. [3 ]
Zhao C. [4 ]
Wang S. [1 ,2 ]
Guo C. [1 ,2 ]
Shi Q. [1 ,2 ]
Ma W. [1 ]
机构
[1] School of Geology and Environment, Xi’an University of Science and Technology, Xi’an
[2] Shaanxi Provincial Key Laboratory of Geological Support for Coal Green Exploitation, Xi’an
[3] School of Architecture and Civil Engineering, Xi’an University of Science and Technology, Xi’an
[4] Xi’an Research Institute Co. Ltd., China Coal Technology and Engineering Group Corp., Xi’an
关键词
Gas permeability measurement method; Low-temperature nitrogen adsorption; Mercury intrusion porosimetry; Nuclear magnetic resonance; Pore structure; Tar-rich coal;
D O I
10.3969/j.issn.1001-1986.2021.03.005
中图分类号
学科分类号
摘要
Extracting oil and refining gas from oil-rich coal is an important measure to make up for the shortage of oil and gas supply in China. The research on pore development characteristics and permeability of tar-rich coal will help to better develop and utilize tar-rich coal. Taking the tar-rich coal in Yushenfu mining area as the research object, this paper studies the multi-scale pore structure and the whole segment pore characterization of tar-rich coal by such methods as low-temperature liquid nitrogen adsorption, mercury intrusion porosimetry, nuclear magnetic resonance and gas permeability measurement method. Based on the test results of multi-scale pore structure of tar-rich coal, this paper discusses the differences between the pore characteristics of tar-rich coal and traditional low-rank coal. The results show that the micropores of tar-rich coal in Yushenfu mining area is extremely well-developed, accounting for over 70% of the total pores, while the macropores and mesopores are relatively underdeveloped, accounting for only 25%-30%. By comparing the results of the nuclear magnetic resonance test with the combined characterization results of low temperature liquid nitrogen adsorption and mercury intrusion porosimetry, it is found that the latter can better characterize the whole segment pores of coal samples. Compared with traditional low-rank coal, tar-rich coal has a larger pore specific surface area of 27.48 m2/g and low-temperature nitrogen adsorption capacity of 40-50 cm3/g, providing an advantage to extract oil and gas for tar-rich coal. © 2021 Meitiandizhi Yu Kantan/Coal Geology and Exploration. All rights reserved
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页码:33 / 41
页数:8
相关论文
共 44 条
  • [1] WANG Shuangming, SUN Qiang, QIAO Junwei, Et al., Geological guarantee of coal green mining[J], Journal of China Coal Society, 45, 1, pp. 8-15, (2020)
  • [2] 2019 domestic and international oil and gas industry development report[M]
  • [3] SUN Yewei, TANG Yuegang, LI Zhengyue, Et al., Occurrence of super high volatile and tar yield coal in China[J], Coal Geology & Exploration, 45, 5, pp. 6-12, (2017)
  • [4] ZHANG Xu, WANG Libin, PEI Xianfeng, Et al., Research progress and key technology of improving coal tar yield and quality by coal pyrolysis[J], Coal Science and Technology, 47, 3, pp. 227-233, (2019)
  • [5] WANG Shuangming, SHEN Yanjun, SUN Qiang, Et al., Scientific issues of coal detraction mining geological assurance and their technology expectations in ecologically fragile mining areas of western China, Journal of Mining and Strata Control Engineering, 2, 4, (2020)
  • [6] CHENG Jingfeng, Shaanxi’s oil-rich coal resources rank first in the country Yulin can “rebuild a Daqing Oil Field”[N], Shaanxi Daily
  • [7] CLAYTON J L, RICE D D, MICHAEL G E., Oil-generating coals of the San Juan Basin, New Mexico and Colorado, USA[J], Organic Geochemistry, 17, 6, pp. 735-742, (1991)
  • [8] YANG Haiping, CHEN Hanping, JU Fudong, Et al., Influence of temperature on coal pyrolysis and char gasification[J], Proceedings of the CSEE, 45, 8, pp. 40-45, (2008)
  • [9] WEN Hu, LU Junhui, XIAO Yang, Et al., Temperature dependence of thermal conductivity, diffusion and specific heat capacity for coal and rocks from coalfield, Thermochimica Acta, 619, pp. 41-47, (2015)
  • [10] LI Xiangchen, KANG Yili, HAGHIGHI M., Investigation of pore size distributions of coals with different structures by nuclear magnetic resonance(NMR) and mercury intrusion porosimetry(MIP), Measurement, 116, pp. 122-128, (2018)