Microstructure and Corrosion Behavior of Ti-Zr-Nb High Entropy Alloy

被引:0
|
作者
Jia Y. [1 ]
Wang P. [1 ]
Zhang W. [1 ]
Wang Y. [1 ]
Dai X. [1 ]
机构
[1] Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu
关键词
Corrosion behavior; High entropy alloy; Microstructure; TiZrNb;
D O I
10.7538/yzk.2021.zhuankan.0238
中图分类号
学科分类号
摘要
The microstructure and corrosion properties of Ti-Zr-Nb high entropy alloys (HEAs) were studied. The results show that the microstructure of the Ti-Zr-Nb alloy was composed of a single BCC phase. Addition of V in Ti-Zr-Nb alloys has little effect on the microstructure of the alloys, but additon of Al will induce ordered B2 phase structure. During the corrosion process in 360 ℃ water and in high temperature steam, the corrosion oxide layer on TiZrNb alloy will spall. Appropriate amount of Al addition (atomic percentage about 15%), will increase the stability of oxide layer formed on Ti-Zr-Nb alloys in 360℃ water and in high temperature steam, and will inhibit the spallation of oxide layer. Large amount of Al addition (atomic percentage is about 25%), corrosion acceleration will happen during the corrosion of alloys in 360℃ water. Certain amount of Al addition will increase the corrosion property of Ti-Zr-Nb alloys, while large content of Al will decrease the corrosion property. © 2021, Editorial Board of Atomic Energy Science and Technology. All right reserved.
引用
收藏
页码:235 / 241
页数:6
相关论文
共 14 条
  • [1] YEH J W, CHEN S K, LIN S J, Et al., Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes, Advanced Engineering Materials, 6, 5, pp. 299-303, (2004)
  • [2] ZHANG Y, ZUO T T, TANG Z, Et al., Microstructures and properties of high-entropy alloys, Progress in Materials Science, 61, pp. 1-93, (2014)
  • [3] SENKOV O N, WILKS G B, SCOTT J M, Et al., Mechanical properties of Nb<sub>25</sub>Mo<sub>25</sub>Ta<sub>25</sub>W<sub>25</sub> and V<sub>20</sub>Nb<sub>20</sub>Mo<sub>20</sub>Ta<sub>20</sub>W<sub>20</sub> refractory high entropy alloys, Intermetallics, 19, pp. 698-706, (2011)
  • [4] LEE C P, CHEN Y Y, HSU C Y, Et al., The effect of boron on the corrosion resistance of the high entropy alloys Al<sub>0.5</sub>CoCrCuFeNiB<sub>x</sub>, Journal of the Electrochemical Society, 154, 8, pp. C424-C430, (2007)
  • [5] LU C Y, NIU L L, CHEN N J, Et al., Enhancing radiation tolerance by controlling defect mobility and migration pathways in multicomponent single-phase alloys, Nature Communications, 7, (2016)
  • [6] SENKOV O N, RAO S, CHAPUT K J, Et al., Compositional effect on microstructure and properties of NbTiZr-based complex concentrated alloys, Acta Materialia, 151, pp. 201-215, (2018)
  • [7] RAO S, AKDIM B, ANTILLON E, Et al., Modeling solution hardening in BCC refractory complex concentrated alloys: NbTiZr, Nb<sub>1.5</sub>TiZr<sub>0.5</sub> and Nb<sub>0.5</sub>TiZr<sub>1.5</sub>, Acta Materialia, 168, pp. 222-236, (2019)
  • [8] KING D J M, CHEUNG S T Y, HUMPHRY-BAKER S A, Et al., High temperature, low neutron cross-section high-entropy alloys in the Nb-Ti-V-Zr system, Acta Materialia, 166, pp. 435-446, (2019)
  • [9] ZHANG W R, LIAW P K, ZHANG Y., Science and technology in high-entropy alloys, Science China Materials, 61, 1, pp. 2-22, (2018)
  • [10] TAKEUCHI A, INOUE A., Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element, Materials Transactions, 46, 12, pp. 2817-2829, (2005)