Research progresses on natural biomass-derived carbon applied in cathode materials for lithium sulfur batteries

被引：0

作者：

Liu W.-H. ^{[1
,2
]}

Liu M.-J. ^{[1
,2
,3
]}

Guo C. ^{[1
]}

Wang S.-J. ^{[1
,2
]}

Li Y. ^{[3
]}

Kong F.-G. ^{[1
,2
]}

机构：

[1] State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shangdong Academy of Sciences), Jinan

[2] Key Lab of Pulp and Paper Science & Technology, Ministry of Education, Qilu University of Technology (Shangdong Academy of Sciences), Jinan

[3] Advanced Materials Institute, Shandong Academy of Sciences, Jinan

来源：

Zhongguo Youse Jinshu Xuebao/Chinese Journal of Nonferrous Metals | 2022年 / 32卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Biomass; Carbon materials; Cathode material; Lithium-sulfur battery; Porous structure;

D O I：

10.11817/j.ysxb.1004.0609.2021-42140

中图分类号：

学科分类号：

摘要：

Lithium-sulfur (Li-S) batteries exhibit high theoretical specific capacity (1675 mA·h/g) and energy density (2600 W·h/kg), thus they are regarded as one of the most promising high energy density storage systems. In spite of these significant advantages, there are several problems and challenges that have to be solved for Li-S batteries. For example, the low electrical conductivity of sulfur, shuttle effect and loss of active substances caused by the polysulfide dissolved in electrolyte, and the volume expansion during the delithium/lithium intercalation reaction, directly lead to low coulombic efficiency, poor cyclical stability, rapid capacity decay, which seriously hinder the commercialization of Li-S batteries. In recent years, natural biomass-derived carbon materials, as sulphur-coated materials, have been widely used as cathode materials, showing excellent electrochemical performance. Their natural advantages of high conductivity, large specific surface area, heterogeneous element doping and low price can greatly improve the utilization rate of sulfur and inhibit the shuttle effect of polysulfide. This paper systematically summarizes the synthesis and optimization of natural biomass-derived carbon materials from diverse sources, and their applications as the hosts for storing sulfur. Moreover, the future research direction of electrode materials is prospected. © 2022, China Science Publishing & Media Ltd. All right reserved.

引用

页码：3096 / 3110

页数：14

共 53 条

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