Effects of preparation methods on the performance of InZr/SAPO-34 composite catalysts for CO2 hydrogenation to light olefins

被引:0
|
作者
Guo S. [1 ,2 ]
Feng L. [2 ]
Yu Z. [1 ,2 ]
Xu D. [3 ]
Liu K. [3 ]
Song X. [2 ]
Cheng Y. [1 ,2 ]
Cao Q. [2 ]
Wang G. [1 ]
Ding M. [3 ]
机构
[1] E-energy Technology Co.,, LTD, Hangzhou
[2] State Grid Zhejiang Electric Power Co., LTD, Research Institute, Hangzhou
[3] School of Power and Mechanical Engineering, Wuhan University, Wuhan
关键词
CO[!sub]2[!/sub] hydrogenation; InZr composite oxide; light olefins; SAPO-34; structure-activity relationship;
D O I
10.1016/S1872-5813(24)60433-0
中图分类号
学科分类号
摘要
Light olefins are of great importance as chemical raw materials, and ethylene is a crucial symbol to evaluate the development level of petrochemical industry. Catalytic hydrogenation of CO2 to light olefins is one of the most vital approaches to utilize CO2 with high added valued. InZr/SAPO-34 composite catalyst shows prominent potential in research and application because of their high light olefins selectivity and high stability in CO2 hydrogenation. In this study, the effects of different preparation methods of InZr/SAPO-34 composite catalyst for CO2 hydrogenation to light olefins were studied in depth. The catalyst prepared by co-precipitation method showed the highest catalytic activity, and the catalyst prepared by sol-gel-precipitation method showed the highest light olefins selectivity. The structure-activity relationship of InZr/SAPO-34 catalysts were revealed by various characterization methods. © 2024 Science Press. All rights reserved.
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页码:790 / 799
页数:9
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