Selectively leaching valuable metals from laterite nickel ore by ammonium chloride

被引:0
|
作者
Li J.-H. [1 ]
Xu Z.-F. [1 ]
Gao Y. [2 ]
Li D.-S. [1 ]
Liu Y. [1 ]
Zhao C.-D. [1 ]
机构
[1] School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou
[2] Henan Institute of Metallurgy Co., Ltd., Zhengzhou
关键词
Ammonium chloride; Ion activity; Laterite nickel ore; Leaching mechanism; Selective leaching;
D O I
10.19476/j.ysxb.1004.0609.2019.05.18
中图分类号
学科分类号
摘要
The hydro-chloride leaching can reduce the impurity ion leaching and consumption of acid effectively. The selectively leaching valuable metals from laterite nickel ore with ammonium chloride hydrochloric acid solution were studied. The results show that when the leaching temperature is 90℃, hydrochloric acid concentration is 2 mol/L, solid-liquid ratio is 1:6 and leaching time is 1.5 h, the leaching rates of nickel, cobalt, manganese and iron are 89.45%, 88.56%, 90.23% and 19.30%, respectively, which achieve selectively leaching in relatively low acid concentration. Based on the selective leaching mechanism research, the addition of chlorine salt is beneficial to dissolution of goethite than other iron minerals in laterite ore, leading to increasing leaching of valuable metals from goethite mineral and suppression leaching of iron from other iron minerals. © 2019, Science Press. All right reserved.
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页码:1049 / 1057
页数:8
相关论文
共 33 条
  • [1] Zhang L., Yang H.-P., Feng A.-S., Cao F., Study on current situation and analysis of supply and demand of global nickel resource, Conservation and Utilization of Mineral Resources, 1, pp. 64-69, (2016)
  • [2] Li X.-M., Bai T.-T., Zhao J.-X., Li W.-F., Li Z.-G., Cui Y.-R., Status and progress of metallurgical technology on laterite nickel ore, Materials Review, 28, 5, pp. 112-116, (2014)
  • [3] Shi J.-F., Wang Z.-X., Hu Q.-Y., Guo H.-J., Li X.-H., Peng W.-J., Recovery of nickel and cobalt from nickel laterite ore by sulfation roasting method using ammonium bisulfate, The Chinese Journal of Nonferrous Metals, 23, 2, pp. 510-515, (2013)
  • [4] Wu Z., Recovery of valuable metals such as nickel and cobalt from sulfuric acid roasting and water leaching of laterite nickel ore, (2011)
  • [5] McDonald R.G., Whittington B.I., Atmospheric acid leaching of nickel laterites review. Part 2. Chloride and bio-technologies, Hydrometallurgy, 91, 1-4, pp. 35-55, (2008)
  • [6] Guo X.-Y., Li D., Tian Q.-H., Shi W.-T., Kinetics of sulfation-roasting of nickel laterite for recovery of nickel and cobalt, Journal of Central South University (Science and Technology), 43, 4, pp. 23-27, (2012)
  • [7] Maragkos I., Giannopoulou I.P., Panias D., Synthesis of ferronickel slag-based geopolymers, Miner Engineering, 22, 2, pp. 196-203, (2009)
  • [8] Mu W.-N., Zhai Y.-C., Desiliconization kinetics of nickeliferous laterite ores in molten sodium hydroxide system, The Chinese Journal of Nonferrous Metals, 20, 2, pp. 330-335, (2010)
  • [9] Qiu S., Che X.-K., Zheng Q., Duan J., Experimental study on laterite-nickel ore with sulfating roasting-water immersion methods, Chinese Journal of Rare Metals, 34, 3, pp. 406-412, (2010)
  • [10] Buyukakinci E., Topkaya Y.A., Extraction of nickel from lateritic ores at atmospheric pressure with agitation leaching, Hydrometallurgy, 97, 1, pp. 33-38, (2009)