Enhancing photocatalytic performance of metal-organic frameworks for CO2 reduction by a bimetallic strategy

Metal-organic frameworks(MOFs) as a type of crystalline heterogeneous catalysts have shown potential application in photocatalytic COreduction.However,MOF catalysts with high efficiency and selectivity are still in pursuit.Herein,by a bimetallic strategy,the catalytic performance of a Co-MOF for photocatalytic COreduction was enhanced.Specifically,the Co-MOF based on 4,5-dicarboxylic acid(HIDC) and4,4’-bipydine(4,4’-bpy) can catalyze COreduction to CO,with high efficiency but relatively low selectivity.After replacement of 2/3 Co(Ⅱ) with Ni(Ⅱ) within Co-MOF,the resulted isostructural CoNi-MOF not only retains high efficiency for photocatalytic COreduction,but also shows enhanced CO selectivity.The CO evolution rate reaches 1160 μmol ghand the CO selectivity reaches as high as 94.6%.The enhanced photocatalytic COreduction performance is supported by theoretical calculation results.This case demonstrates that bimetallic strategy is an effective mean to optimize the catalytic performance of MOF catalysts for photochemical COreduction.