Adsorption of uranium (VI) complexes with polymer-based spherical activated carbon

被引:0
|
作者
Kopinke, Frank-Dieter [1 ]
机构
[1] UFZ Helmholtz Ctr Environm Res, Dept Tech Biogeochem, D-04318 Leipzig, Germany
关键词
Adsorption; Conversion of adsorption constants; Thermodynamic adsorption parameters;
D O I
10.1016/j.watres.2024.122031
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Calculation of thermodynamic parameters of adsorption such as Gibbs free energy Delta G(ads)(degrees) from experimentally determined adsorption data can be helpful for elucidation of sorption mechanisms. This approach includes the transformation of adsorption coefficients K-d or K-L into dimensionless standard adsorption constants K-ads [-]. The present comment reveals recently published misleading approaches and offers thermodynamically sound alternatives.
引用
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页数:2
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