N-Alkylation of amines with primary/secondary alcohols using a novel cobalt(ii) inverse triazolyl-pyridine complex

被引：2

作者：

Shekhawat, Bhawana ^{[1
]}

Gahlaut, Puneet Singh ^{[1
]}

Gautam, Deepak ^{[1
]}

Jana, Barun ^{[1
]}

机构：

[1] Malaviya Natl Inst Technol Jaipur, Dept Chem, Organometall & Supramol Chem Lab, JLN Marg, Jaipur 302017, Rajasthan, India

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 65期

关键词：

SECONDARY ALCOHOLS; AMINATION; CATALYST;

D O I：

10.1039/d4cc01996b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report a highly effective homogeneous methodology for the N-alkylation of amines with primary and secondary alcohols using a Co(II)-complex of an inverse triazolyl-pyridine ligand. The developed methodology tolerates various functional groups to produce the desired N-alkylated products in up to 98% yield. A number of control experiments establish that the developed methodology follows a hydrogen auto-transfer (HAT) pathway.

引用

页码：8581 / 8584

页数：4

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