Study on the UV aging resistance of ZnO-modified epoxy resin by experiments and MD simulation

被引:0
|
作者
Zhang, Hao [1 ]
Chu, Xiaocheng [1 ]
Ding, Qingjun [1 ]
Zhao, Gai [1 ]
Li, Huafeng [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, State Key Lab Mech & Control Aerosp Struct, Nanjing, Peoples R China
来源
POLYMER ENGINEERING AND SCIENCE | 2024年 / 64卷 / 12期
基金
中国国家自然科学基金;
关键词
epoxy resins; molecular dynamics; UV radiation; MOLECULAR-DYNAMICS;
D O I
10.1002/pen.26957
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study investigates the impact of zinc oxide nanoparticles on epoxy resin systems and the ultraviolet (UV) aging resistance of modified epoxy resin composites using molecular dynamics (MD) simulations and experimental methods. Initially, various epoxy resin cross-linking models are established through MD simulations to understand the influence of different nano ZnO contents on resin modification, further validated by experiments. Subsequently, the UV radiation resistance of nano ZnO-epoxy resin composites is assessed by subjecting them to high-intensity UV radiation equivalent to 3 years of natural environmental conditions, analyzing changes in tensile properties, impact performance, hardness, and glass transition temperature of epoxy resin before and after UV radiation exposure. The findings suggest that the addition of nano zinc oxide reduces the impact of UV radiation on epoxy resin, with optimal UV radiation resistance observed at a nano zinc oxide mass fraction of 0.3 wt%.
引用
收藏
页码:5903 / 5914
页数:12
相关论文
共 50 条
  • [1] Experimental and numerical study on CuO/ZnO-modified aramid fabric for ballistic and UV radiation protection
    Liu, Li
    Huang, Fenglei
    Xu, Yaojie
    Lan, Xuke
    Huang, Guangyan
    POLYMER TESTING, 2024, 139
  • [2] MD Simulation of Crosslinked Epoxy Resin At Different Temperatures
    Zhang, Miao
    Yang, Ping
    PROGRESS IN MATERIALS AND PROCESSES, PTS 1-3, 2013, 602-604 : 747 - 750
  • [3] Study on the epoxy resin heat resistance modified by polyamide acid
    Zhou, Hao-Ran
    Kong, De-Zhong
    Liu, Da
    Hunan Daxue Xuebao/Journal of Hunan University Natural Sciences, 2009, 36 (07): : 56 - 58
  • [4] Study of the physical aging of an epoxy/cycloaliphatic amine resin modified with ABS
    Ramírez, C
    Abad, MJ
    Barral, L
    Cano, J
    Díez, FJ
    López, J
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2002, 70 (01): : 85 - 92
  • [5] Study of the physical aging of an epoxy/cycloaliphatic amine resin modified with abs
    C. Ramírez
    M. J. Abad
    L. Barral
    J. Cano
    F. J. Díez
    J. López
    Journal of Thermal Analysis and Calorimetry, 2002, 70 : 85 - 92
  • [6] Humid heat aging of biphenyl epoxy resin: a combined study of experiments and simulations
    Wu, Yunjian
    Zhou, Zhiyuan
    Guo, Yifan
    Fang, Rui
    Zhang, Xiaoxing
    ADVANCED COMPOSITE MATERIALS, 2025, 34 (02) : 195 - 209
  • [7] Study of Modified Epoxy Resin
    Ren, Shuiyun
    Huang, Hongjun
    Du, Zhihong
    PROCEEDINGS OF THE 2015 INTERNATIONAL CONFERENCE ON MATERIALS, ENVIRONMENTAL AND BIOLOGICAL ENGINEERING, 2015, 10 : 660 - 664
  • [8] Insights into the pyrolysis mechanisms of epoxy resin polymers based on the combination of experiments and ReaxFF-MD simulation
    Xu, Ming-xin
    Di, Jin-yi
    Wu, Ya-chang
    Meng, Xiang-xi
    Jiang, Hao
    Li, Ji-hong
    Lu, Qiang
    CHEMICAL ENGINEERING JOURNAL, 2023, 473
  • [9] Physical aging of polydimethylsiloxane-modified epoxy resin
    Lee, SS
    Kim, SC
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 69 (07) : 1291 - 1300
  • [10] Investigation on Thermal Properties of Crosslinked Epoxy Resin by MD Simulation
    Liao, Ningbo
    Zhang, G. Q.
    Pavel, Dumitru
    van der Sluis, Olaf
    Jansen, K. M. B.
    Ernst, L. J.
    EUROSIME 2009: THERMAL, MECHANICAL AND MULTI-PHYSICS SIMULATION AND EXPERIMENTS IN MICRO-ELECTRONICS AND MICRO-SYSTEMS, 2009, : 546 - 549