An in-depth study of integrating cascaded photocatalytic H2O2 generation and activation with solar-driven interfacial evaporation for in-situ organic contaminant remediation

Integrating cascaded photocatalytic H2O2 generation and subsequent activation of H2O2 (into center dot OH radicals) with solar-driven interfacial evaporation techniques offers an effective and sustainable approach for in-situ treating water contaminated with organic substances. Unlike traditional water-dispersed catalysts, the interfacial evaporation approach presents unique challenges in photocatalytic reactions. We explored these dynamics using an AgI/PPy/MF interfacial photothermal set, achieving H2O2 production efficiency (approximately 1.53 mM/g/h) - three times higher than submerged counterparts. This efficiency is attributed to exceptional solar light absorption (about 95 %), a significant surface photothermal effect (raising temperatures by approximately 36 degrees C), and enhanced oxygen availability (38 times more than in water), all characteristic of the interfacial system. The insitu activation of H2O2 into center dot OH notably improves the degradation of organic pollutants, achieving up to 99 %