Polytypism of incommensurately modulated structures of crystalline bromine upon molecular dissociation under high pressure

被引:3
|
作者
Yin, Yuqing [1 ,2 ,3 ]
Aslandukov, Andrey [1 ,4 ]
Bykov, Maxim [5 ]
Laniel, Dominique [6 ,7 ]
Aslandukova, Alena [4 ]
Pakhomova, Anna [8 ]
Fedotenko, Timofey [9 ]
Zhou, Wenju [1 ]
Akbar, Fariia Iasmin [1 ,4 ]
Hanfland, Michael [8 ]
Glazyrin, Konstantin [9 ]
Giacobbe, Carlotta [8 ]
Bright, Eleanor Lawrence [8 ]
Garbarino, Gaston [8 ]
Jia, Zhitai [2 ]
Dubrovinskaia, Natalia [1 ,3 ]
Dubrovinsky, Leonid [4 ]
机构
[1] Univ Bayreuth, Lab Crystallog, Mat Phys & Technol Extreme Condit, D-95440 Bayreuth, Germany
[2] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[3] Linkoping Univ, Dept Phys Chem & Biol IFM, SE-58183 Linkoping, Sweden
[4] Univ Bayreuth, Bayer Geoinst, D-95440 Bayreuth, Germany
[5] Univ Cologne, Inst Inorgan Chem, Greinstr 6, D-50939 Cologne, Germany
[6] Univ Edinburgh, Ctr Sci Extreme Condit, Edinburgh EH9 3FD, Scotland
[7] Univ Edinburgh, Sch Phys & Astron, Edinburgh EH9 3FD, Scotland
[8] European Synchrotron Radiat Facil, F-38000 Grenoble, France
[9] Deutsch Elektronen Synchrotron DESY, Notkestr 85, D-22607 Hamburg, Germany
关键词
PHASE; CRYSTALLOGRAPHY; IODINE;
D O I
10.1103/PhysRevB.110.104111
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polytypism of incommensurately modulated structures was hitherto unobserved. Here, it was found in solid bromine and iodine upon molecular dissociation under pressure up to 112 GPa. Single-crystal synchrotron x-ray diffraction in laser-heated diamond anvil cells revealed a number of allotropes of bromine and iodine, including polytypes of Br-III gamma (Fmmm(00 gamma)s00) with gamma varying within 0.18 to 0.3, coexisting at a given pressure. This finding opens a research area in the field of solid-solid phase transitions, disordered states of solid matter, and high-pressure structural studies.
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页数:20
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