Modeling the thermo-oxidative aging effects on fatigue life of natural rubber using a continuum damage mechanics approach

Thermo-oxidative aging (TOA) significantly impacts the fatigue life of rubbers by reducing the fatigue strength and modifying the slope of the Wo<spacing diaeresis>hler curve, rendering traditional time-temperature superposition methods inadequate. In this work, we aim to develop a model capable of predicting the effect of TOA on the fatigue properties of rubbers. For this purpose, dumbbell specimens of natural rubber (NR) were subjected to aging in an air-vented oven at different temperatures prior to mechanical testing. Tensile tests were conducted to quantify the aging effects on a microscale network parameter known as elastically active chains (EAC) density, along with determining ultimate properties such as the stress and strain at break. By using a time-temperature equivalence and the Arrhenius shift factor, master curves were constructed for both EAC density and ultimate properties. Subsequently, the fracture properties of the aged material were predicted using an energy limiter approach whose evolution follows that of EAC density. Furthermore, a relationship between the parameters of the continuum damage mechanics (CDM) approach (specifically, the power law parameters of the Wo<spacing diaeresis>hler curve) and the fracture properties was proposed, resulting in accurate estimates of the fatigue life regardless of the aging conditions. Satisfactory agreement was observed between the model predictions and the data for nine aging conditions encompassing four different temperatures. The CDM approach also allows assessing the evolution of mechanical damage within the material influenced by TOA. The novelty of this approach lies in establishing a direct relationship between fatigue and fracture properties. Moreover, this is the first time to the best of our knowledge that TOA has been explicitly incorporated into a fatigue life prediction model via the evolution of the EAC density.