End-of-life vehicle dismantling activity emits large quantities of phthalates and their alternatives: New insights on environmental sources and co-exposure risks

被引:0
|
作者
Shi, Yumeng [1 ]
Zhao, Leicheng [2 ]
Zheng, Jie [1 ]
Ding, Ran [1 ]
Li, Keyi [1 ]
Zhao, Hongzhi [1 ]
Baqar, Mujtaba [1 ,3 ]
Zhu, Hongkai [1 ]
Cheng, Zhipeng [1 ]
Sun, Hongwen [1 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, MOE Key Lab Pollut Proc & Environm Criteria, Tianjin 300350, Peoples R China
[2] Henan Normal Univ, Sch Environm, Key Lab Yellow River & Huai River Water Environm &, Henan Key Lab Environm Pollut Control,Minist Educ, Xinxiang 453007, Peoples R China
[3] Govt Coll Univ, Sustainable Dev Study Ctr, Lahore 54000, Pakistan
基金
中国国家自然科学基金;
关键词
End-life-vehicles dismantling; PAEs; NPAEs; Dust; Occupational exposure; Molecular docking; HUMAN EXPOSURE; INDOOR DUST; PLASTICIZERS; ESTERS; IMPACT; SKIN;
D O I
10.1016/j.envint.2024.108933
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Automotive interiors have been identified as significant sources of various chemicals, yet their occupational hazards for end-of-life vehicle (ELV) dismantlers remain poorly characterized. Herein, eight classes of plasticizers, including 11 phthalates esters (PAEs) and 16 non-phthalates esters (NPAEs), were detected in dust samples from inside and outside ELV dismantling workshops. Moreover, indoor dust from ordinary households and university dormitories was compared. The indoor dust from the ELV dismantling workshops contained the highest concentrations of plasticizers (median: 594 mu g/g), followed by ordinary households (296 mu g/g), university dormitories (186 mu g/g), and outdoor dust (157 mu g/g). PAEs remained the dominant plasticizers, averaging 11.7-fold higher than their NPAE alternatives. Specifically, diisononyl phthalate and trioctyl trimellitate were notably elevated in workshop dust, being 15.5 and 4.78 times higher, respectively, than in ordinary household dust, potentially indicating their association with ELV dismantling activities. The estimated daily intake of occupational ELV dismantling workers was up to five times higher than that of the general population. Moreover, certain dominant NPAEs demonstrated nuclear receptor interference abilities comparable to typical PAEs, suggesting potential toxic effects. This study is the first to demonstrate that ELV dismantling activities contribute to the co-emission of PAEs and NPAEs, posing a substantial risk of exposure to workers, which warrants further investigation.
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页数:9
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