Red luminescence CaSiO3:Eu3+ eco-friendly nontoxic phosphor derived from biomass for display and latent finger print applications

被引:0
|
作者
Raju, M. Krishnam [1 ,5 ]
Yadav, Pooja [1 ]
Gangadhar, M. [1 ]
Patel, Sushil [1 ]
Samudrala, Raj Kumar [2 ]
Kumari, Anita [3 ]
Bramanandam, M. [3 ]
Azeem, P. Abdul [1 ,4 ]
机构
[1] Natl Inst Technol Warangal, Dept Phys, Warangal 506004, Telangana, India
[2] SR Univ, Dept Phys, Warangal 506371, Telangana, India
[3] Univ Hyderabad, Sch Life Sci, Dept Biochem, Hyderabad 50046, Telangana, India
[4] Natl Inst Technol Warangal, Ctr Excellence Glass Sci & Technol, Warangal 506004, Telangana, India
[5] Parul Univ, Fac Engn & Technol, Dept Elect & Commun Engn, Vadodara 391760, Gujarat, India
关键词
Hydrothermal; Luminescence; Latent finger print; RICE HUSK ASH; EU3+; PHOTOLUMINESCENCE; SILICA; NANOPARTICLES; PERFORMANCE; DELIVERY; POWDERS;
D O I
10.1016/j.rechem.2024.101838
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Red luminescent Eu3+ activated CaSiO3 phosphor has been prepared by facile green synthesis hydrothermal route using biomass. Future technologies will be required to synthesize on a massive scale using quick, easy, and affordable ways. The current study deals with the preparation of CaSiO3:Eu3+ using egg shell and rice husk ash. The synthesized powders had a single phased monoclinic structure with space group P1 21/C1. It has been found that addition of Eu3+ ion dopant causes decrease in the optical energy band gap. The phosphor exhibits the intense peak at 612 nm corresponds to 5 D 0 -> 7 F 2 of the Eu3+ anions upon excitation at 392 nm. The lifetimes ranged from 1.90 to 3.53 ms. With an increase in Eu3+ concentration, emission was tuned towards the red area of the CIE diagram. In order to detect hidden fingerprints on flat surfaces using the powder dusting approach, the CaSiO3:Eu3+ effectiveness was also evaluated. The nontoxicity of CaSiO3:Eu3+ was validated by carrying out a cell viability test on MG 63 cell lines. These outcomes demonstrated that the luminescent CaSiO3:Eu3+ can be used as potential material for display, security encoding, and latent fingerprint applications.
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页数:10
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