Fe(<sc>iii</sc>)-catalyzed p-selective C-H bond chalcogenation of phenols

被引：1
|
作者：
Paul, Biprajit [1 ]
Ghosh, Sayak [1 ]
Das, Surajit [1 ]
Chatterjee, Indranil [1 ]
机构：
[1] Indian Inst Technol Ropar, Dept Chem, Nangal Rd, Rupnagar 140001, Punjab, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2024年 / 22卷 / 40期
关键词：
METAL; INHIBITOR; SULFIDES; ANALOGS; SE;
D O I：
10.1039/d4ob01382d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient, eco-friendly, and scalable protocol has been introduced for the p-selective C-X (X = Se/S) bond formation of phenols employing earth-abundant, less-toxic Fe(iii)-catalysts and the green solvent ethanol without using any directing template, stabilizing ligands, oxidants, or additives. The key attraction lies in the impressive p-selectivity with moderate to good yields, wide functional group compatibility under mild aerobic reaction conditions, and the synthetic modification of the products towards value-added molecules.
引用
收藏
页码：8133 / 8137
页数：5
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