Influence of Ferrosilicon Addition on Silicon-oxygen Equilibria in High-silicon Steels

被引：1

作者：

Pindar, Sanjay ^{[1
]}

Pande, Manish Marotrao ^{[1
]}

机构：

[1] Indian Inst Technol Bombay Powai, Dept Met Engn & Mat Sci, Mumbai 400076, Maharashtra, India

来源：

ISIJ INTERNATIONAL | 2024年 / 64卷 / 07期

关键词：

deoxidation; ferrosilicon; Si-O equilibria; high-silicon steel;

D O I：

10.2355/isijinternational.ISIJINT-2024-018

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The role of impurities introduced to the steel melt through ferrosilicon addition is of considerable impor-tance in determining the steel cleanness of Si-killed, Si-alloyed steel grades. The silicon requirement is often met with ferrosilicon (FeSi) addition at the industrial scale. In the present study, a detailed investiga-tion of commercial purity ferrosilicon (FeSi) alloy has been conducted to assess its impurity content. Alu-minium and titanium were found to be the main impurities among others. Si-O equilibria in liquid steel has been established at 1 873 K using FeSi alloy for a wide range of silicon concentration to examine the influence of its impurities. The actual Si-O equilibria established through FeSi addition was compared with true Si-O equilibria which was established using High-purity silicon (HPS) addition. It has been observed that impurities (mainly aluminium and titanium) from FeSi perturbed the true Si-O equilibria. Thermody-namic and kinetic considerations pertaining to this deviation have been elaborated in the present study

引用

页码：1143 / 1154

页数：128

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[1] Silicon-oxygen equilibria in liquid iron
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[6] Development of Austempered High-Silicon Cast Steels.
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