Sulfamic acid as pickling agent for zinc and iron based alloys and its corrosion inhibition using inhibitors: a comprehensive review

被引:0
|
作者
Shetty, Chaithra [1 ]
Kumari, P. Preethi [1 ]
机构
[1] Manipal Acad Higher Educ, Manipal Inst Technol, Dept Chem, Manipal, India
关键词
Sulfamic acid; adsorption; tafel polarisation; electrochemical impedance; corrosion inhibition; MILD-STEEL; ELECTROCHEMICAL-BEHAVIOR; CARBON-STEEL; CATALYST; EFFICIENT; EXTRACT; NACL;
D O I
10.1080/00084433.2024.2397607
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Pickling agents such as sulfamic acid (NH2SO3H) are favoured due to their distinct ability to break down tough deposits and scales. Sulfamic acid is less corrosive than other acids, such as hydrochloric, sulfuric and nitric acids, and it does not release any toxic fumes when used. Nevertheless, even though it is a mild acid, it can lead to deterioration of many metallic materials in its lower pH range; hence, it needs to be regulated to enhance its corrosion resistance. Therefore, organic compound-based corrosion inhibitors of natural and synthetic origin are widely used to prevent corrosive damage to metallic surfaces in such electrolytes. Recent studies on the corrosion inhibition behaviour of various zinc and iron-based alloys in sulfamic acid media using various inhibitors are included in this article. The various techniques employed to explore the electrochemical behaviour of these materials in the presence of various inhibitors and their inhibition potentials are discussed. Additionally, the corrosion characteristics of steel and zinc in sulfamic acid and the interaction of inhibitor molecules with the metal surface, and mode of adsorption are also discussed in detail. Les agents de d & eacute;capage tels que l'acide sulfamique (NH2SO3H) sont favoris & eacute;s en raison de leur capacit & eacute; distincte & agrave; d & eacute;sagr & eacute;ger les d & eacute;p & ocirc;ts et les & eacute;cailles tenaces. De plus, la norme principale, l'acide sulfamique (SA), est facilement formul & eacute;e et accessible sous forme solide. L'acide sulfamique est moins corrosif que d'autres acides, tels que les acides chlorhydrique, sulfurique et nitrique et il ne rel & acirc;che pas de fum & eacute;es toxiques lorsqu'on l'utilise. N & eacute;anmoins, m & ecirc;me s'il s'agit d'un acier doux, il peut entra & icirc;ner la d & eacute;t & eacute;rioration de plusieurs mat & eacute;riaux m & eacute;talliques dans sa gamme de pH inf & eacute;rieure; ainsi, il doit & ecirc;tre r & eacute;glement & eacute; pour am & eacute;liorer sa r & eacute;sistance & agrave; la corrosion. Par cons & eacute;quent, les inhibiteurs de corrosion & agrave; base de compos & eacute;s organiques d'origine naturelle et synth & eacute;tique sont largement utilis & eacute;s pour emp & ecirc;cher les dommages corrosifs des surfaces m & eacute;talliques dans ces & eacute;lectrolytes. Dans cet article, on inclut des & eacute;tudes r & eacute;centes sur le comportement d'inhibition de la corrosion de divers alliages & agrave; base de zinc et de fer dans les milieux d'acide sulfamique utilisant divers inhibiteurs. On discute des diverses techniques utilis & eacute;es pour explorer le comportement & eacute;lectrochimique de ces mat & eacute;riaux en pr & eacute;sence de divers inhibiteurs ainsi que leurs potentiels d'inhibition. En plus, on discute & eacute;galement en d & eacute;tail les caract & eacute;ristiques de corrosion de l'acier et du zinc dans l'acide sulfamique, l'interaction des mol & eacute;cules inhibitrices avec la surface du m & eacute;tal ainsi que le mode d'adsorption. Une explication br & egrave;ve de la caract & eacute;risation de la surface et des aspects th & eacute;oriques est fournie pour corroborer les r & eacute;sultats exp & eacute;rimentaux.
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页数:10
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