Influence of the Structure of Hydrothermal-Synthesized TiO2 Nanowires Formed by Annealing on the Photocatalytic Reduction of CO2 in H2O Vapor

被引:0
|
作者
Tarasov, Andrey M. [1 ]
Sorokina, Larisa I. [1 ]
Dronova, Daria A. [1 ]
Volovlikova, Olga [1 ]
Trifonov, Alexey Yu. [1 ,2 ]
Itskov, Sergey S. [1 ]
Tregubov, Aleksey V. [3 ]
Shabaeva, Elena N. [3 ]
Zhurina, Ekaterina S. [3 ]
Dubkov, Sergey V. [1 ]
Kozlov, Dmitry V. [3 ]
Gromov, Dmitry [1 ,4 ]
机构
[1] Natl Res Univ Elect Technol MIET, Inst Adv Mat & Technol, Bld 1, Shokin Sq, Moscow 124498, Russia
[2] Natl Res Ctr Kurchatov Inst, 1 Kurchatov Sq, Moscow 123182, Russia
[3] Ulyanovsk State Univ, SP Kapitsa Sci Technol Res Inst, 42 Leo Tolstoy St, Ulyanovsk 432017, Russia
[4] IM Sechenov First Moscow State Med Univ, Inst Bion Technol & Engn, Bolshaya Pirogovskaya 2, Moscow 119435, Russia
基金
俄罗斯科学基金会;
关键词
hydrothermal synthesis; TiO2; photocatalysis; CO2; photoreduction; ANATASE; OXIDATION; PHASE; CALCINATION; TEMPERATURE; HYDROGEN; DIOXIDE; TOLUENE;
D O I
10.3390/nano14161370
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The present study investigates the photocatalytic properties of hydrothermally synthesized TiO2 nanowires (NWs) for CO2 reduction in H2O vapor. It has been demonstrated that TiO2 NWs, thermally treated at 500-700 degrees C, demonstrate an almost tenfold higher yield of products compared to the known commercial powder TiO2 P25. It has been found that the best material is a combination of anatase, TiO2-B and rutile. The product yield increases with increasing heat treatment temperature of TiO2 NWs. This is associated with an increase in the degree of crystallinity of the material. It is shown that the best product yield of the CO2 reduction in H2O vapor is achieved when the TiO2 NW photocatalyst is heated to 100 degrees C.
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页数:15
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