Experimental investigation and numerical simulation of chloride diffusion in rubber concrete under dry-wet cycles

Chloride erosion caused by the dry-wet cycles is one of the most significant factors leading to durability problems in concrete structures. In this paper, the diffusion behavior of chloride in rubber concrete with varying rubber content is studied by experimental investigation and numerical simulation based on setting up artificial dry-wet cycles exposure conditions. The determination of chloride concentration in rubber concrete is achieved through chloride concentration titration, and as a result, the surface chloride concentration and the apparent chloride diffusion coefficient are expressed as a function of time, thus providing a theoretical guide for Comsol Multiphysics to perform numerical simulations. The findings indicate that the chloride diffusion behavior in rubber concrete complies with Fick's second law and that rubber can effectively reduce the diffusion rate of chloride in rubber concrete. Furthermore, the surface chloride concentration and apparent chloride diffusion coefficient are fitted with high accuracy according to the experimental data, which ensures the precision of the numerical simulation. In addition, numerical simulation results indicate that the diffusion of chloride in rubber concrete is impeded by the aggregate, that is, chloride diffusion is faster in areas where the local aggregate volume fraction is small. Also, it is evident that the presence of interfacial transition zone (ITZ) negatively affects the resistance of rubber concrete to chloride diffusion.