Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts

被引:0
|
作者
Jia, Hailang [1 ]
Li, Hongcheng [1 ]
Ji, Pengcheng [1 ]
Teng, Yang [1 ]
Guan, Mingyun [1 ]
机构
[1] Jiangsu Univ Technol, Sch Chem & Chem Engn, Changzhou 213001, Jiangsu, Peoples R China
关键词
oxygen reduction reaction; carbon nanotube; N-doped; Co3O4; GRAPHENE;
D O I
10.11862/CJIC.20230402
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Carbon nanotube (CNT) was used as raw materials, loaded with vitamin B-12, and then subjected to simple pyrolysis to obtain a nitrogen doped carbon nanotube (N/CNT) and loaded with low content Co3O4 nanoparticles (Co3O4@N/CNT) as an oxygen reduction reaction electrocatalyst. Due to the uniformly dispersed Co3O4 nanoparticles and N-doped effect, Co3O4@N/CNT exhibited excellent oxygen reduction reaction catalytic performance, with a half wave potential of 0.844 V (vs RHE), surpassing the performance of commercial Pt/C (0.820 V vs RHE). Compared to Pt/C, the zinc-air battery based on Co3O4@N/CNT exhibited better discharge performance and cycle stability.
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页数:200
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