NIR-induced photothermal-responsive shape memory polyurethane for versatile smart material applications

Stimuli responsiveness has been an attractive feature of smart material design, allowing the chemical and physical properties of the materials to change in response to small environmental variations. The versatile shape memory polyurethane (SMPU) has been advanced into thermally-responsive SMPU, enabling its use in neurovascular stents, smart fibers for compression garments, and thermal-responsive components for aircraft and aerospace structures. While thermally-induced SMPU materials exhibit excellent shape recovery and fixity, they encounter limitations such as long response times, energy-intensive heating processes, and potential damage to heat-sensitive components, hindering their wide application. Thus, SMPU has further advanced into a photothermal-responsive material by incorporating photothermal agents into the polymer matrix, offering faster response times, compatibility with heat-sensitive materials, and enhanced mechanical properties, expanding the versatility and applicability of shape memory technology. This review focuses on the classes of NIR-induced photothermal agent used in SMPU systems, their synthesis methods, and photothermal-responsive mechanism under NIR-light, which offers a dual responsiveness to the host SMPU. The advantages and limitations of NIR-induced photothermal SMPU are reviewed, and challenges in their development are discussed. A review of recent advances of NIR-light induced photothermal-responsive shape memory polyurethane for industrial and medical applications. It covers the classes of photothermal agents, responsive mechanism, synthesis, advantages, and challenges.