Dissolved Organic Matter-Mediated Photosensitized Activation of Monochloramine for Micropollutant Abatement in Wastewater Effluent

Utilizing solar light and water matrix components in situ to reduce the chemical and energy demands would make treatment technologies more sustainable for micropollutant abatement in wastewater effluents. We herein propose a new strategy for micropollutant abatement through dissolved organic matter (DOM)-mediated photosensitized activation of monochloramine (NH2Cl). Exposing the chlorinated wastewater effluent with residual NH2Cl to solar irradiation (solar/DOM/NH2Cl process) degrades six structurally diverse micropollutants at rate constants 1.26-34.2 times of those by the solar photolysis of the dechlorinated effluent (solar/DOM process). Notably, among the six micropollutants, the degradation rate constants of estradiol, acetaminophen, bisphenol A, and atenolol by the solar/DOM/NH2Cl process are 1.13-4.32 times the summation of those by the solar/DOM and solar/NH2Cl processes. The synergism in micropollutant degradation is attributed to the generation of reactive nitrogen species (RNS) and hydroxyl radicals (HO<bold>(<middle dot>)</bold>) from the photosensitized activation of NH2Cl. Triplet state-excited DOM ((DOM)-D-3*) dominates the activation of NH2Cl, leading to the generation of RNS, while HO<bold>(<middle dot>)</bold> is produced from the interactions between RNS and other photochemically produced reactive intermediates (e.g., O-2(<bold><middle dot></bold>-) and DOM<bold>(<middle dot>)</bold>(+/<bold><middle dot></bold>-)). The findings advance the knowledge of DOM-mediated photosensitization and offer a sustainable method for micropollutant abatement in wastewater effluents containing residual NH2Cl.