Kinetic modelling of non-equilibrium plasma enhanced catalytic ammonia decomposition

It is important for the usage of ammonia as energy carrier to achieve ammonia decomposition at low temperature. In the present study, a reactor model of plasma catalytic ammonia decomposition over Fe catalyst at atmospheric pressure is developed in the aspect of plasma and chemical synergies kinetics. The plasma catalytic model accounted for multiple physical mechanisms in electronic and vibrational plasma kinetics and detailed ammonia decomposition mechanisms on the catalyst surface. In addition, a novel view that identify the surface chemisorption enhancement by plasma attributed to charge transfer via EMSI (electronic metal-support interaction) effect is highlighted. The result shows that the synergetic effect of plasma and thermal-catalyst is much greater than that of plasma or catalyst alone on ammonia decomposition, especially at low temperature. It is revealed that the surface desorption of nitrogen is still the rate-limiting step. Moreover, the numerical results also indicate that Langmuir-Hinshelwood reaction via 2 N(s)= >N-2 is more likely to dominate the surface desorption of nitrogen in the presence of plasma rather than Eley-Rideal reaction via N + N(s)= >N-2 . At low electric field, there are infrequent free radicals (NH 2 , NH and N) and few vibrational ammonia (NH3(v)) generated by the plasma, thus considering that the adsorbed ammonia only undergoes a three-step dehydrogenation reaction. As a consequence, the rate of surface nitrogen desorption with plasma is greater than that with catalyst alone since plasma promotes the chemisorption process of ammonia. This work provides new fundamental insights into the synergistic effect of plasma and catalyst, as well as the direction for the ammonia decomposition catalyst design in plasma.