(Mn, Co, Cu)-Ce solid solution for efficient degradation of tetracycline via photo-fenton-like process

被引:0
|
作者
Pu, Jianglin [1 ,2 ,3 ]
Luo, Yi [1 ,2 ,3 ]
Han, Hongru [1 ,2 ,3 ]
Mushtaq, Muhammad Arslan [1 ,2 ,3 ]
Jia, Yuefa [1 ,2 ,3 ]
机构
[1] Changan Univ, Sch Water & Environm, Xian 710054, Peoples R China
[2] Changan Univ, Key Lab Subsurface Hydrol & Ecol Effects Arid Reg, Minist Educ, Xian 710054, Peoples R China
[3] Changan Univ, Key Lab Ecohydrol & Water Secur Arid & Semiarid Re, Minist Water resources, Xian 710054, Peoples R China
关键词
(Mn; Co; Cu)-Ce solid solution; Photo-Fenton-like; Nanoparticles; Semiconductors; CEO2;
D O I
10.1016/j.matlet.2024.137063
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Herein, (Mn, Co, Cu)-Ce solid solution (MnCeOx, CoCeOx and CuCeOx) catalysts were successfully synthesized and applied in a Photo-Fenton-like system for tetracycline hydrochloride (TCH) degradation. The CuCeOx/H2O2 system displayed the best catalytic activity compared with CoCeOx/H2O2 and MnCeOx/H2O2 systems under visible light irradiation. The high TCH degradation performance of CuCeOx/H2O2 system was mainly ascribed to the synergistic effect of photocatalysis and Fenton-like reaction, which accelerated the cycle between Cu2+ and Cu+ by using the photoinduced carriers and facilitated the generation of reactive radicals. Furthermore, the possible mechanism of MnCeOx, CoCeOx and CuCeOx photocatalysts activating H2O2 toward TCH degradation was proposed.
引用
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页数:5
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