The production of activated carbon from Acacia erioloba seedpods via phosphoric acid activation method for the removal of methylene blue from water

被引:9
|
作者
Daniel, Likius Shipwiisho [1 ,2 ]
Rahman, Ateeq [1 ]
Hamushembe, Mirjam Ndakola [1 ]
Kapolo, Paulus [1 ]
Uahengo, Veikko [1 ]
Jonnalagadda, Sreekantha Babu [3 ]
机构
[1] Univ Namibia, Dept Phys Chem & Mat Sci, Postbag 13301, Windhoek, Namibia
[2] Univ Namibia, Ctr Res Serv, Multidisciplinary Res Serv, Postbag 13301, Windhoek, Namibia
[3] Univ KwaZulu Natal, Sch Chem & Phys, ZA-4000 Durban, South Africa
来源
关键词
Activated carbon; Proximate analysis; Acacia seed pods; Brunauer; -Emmett; -Teller; Langmuir model Freundlich model; Phosphoric acid; BASIC DYE; CHEMICAL ACTIVATION; COCONUT SHELL; ADSORPTION; EQUILIBRIUM; BIOMASS; STONES; H3PO4; OPTIMIZATION; PYROLYSIS;
D O I
10.1016/j.biteb.2023.101568
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Wastewater treatment requires a lot of granular activated carbon to absorb the dissolved organic components. This article describes a low-cost process for making highly active adsorption activated carbons from biomass, which could be used for wastewater treatment. A one-step carbonization and chemical activation with phosphoric acid at 500 degrees C produced low-cost acacia-derived porous activated carbons. The activated carbons ' moisture, ash, volatile matter, and fixed carbon content were determined using proximate analysis. The activated carbon ' s adsorption qualities were also determined by studying its bulk density, surface morphology, power of hydrogen, iodine number, and methylene blue number index. To test the produced activated carbons for water treatment, batch adsorption dynamics were performed at room temperature for the removal of methylene blue from aqueous solution. Compared to activation using H 2 SO 4 , H 3 PO 4 proves superior in generating welldeveloped pores, leading to a mesoporosity and microporosity structure with a larger surface area and high adsorption capacity. Brunauer - Emmett - Teller determined the sample ' s specific surface area, which was found to be 387 m 2 /g. The iodine number for 50, 100, and 200 mu m activated carbon particles size was 620, 592, and 632 mg/g, respectively. The adsorption of MB on AC material better fits with Langmuir ' s adsorption isotherm; hence, particles are adsorbed on well-pronounced heterogeneous surfaces. The sips model is found to best represent the equilibrium data with R 2 values of 0.994, suggesting the heterogeneous surface adsorption of MB on AC. Therefore, the adsorption of AC by MB involves physical and chemical processes. The produced AC hence appears to remove dissolved organic contaminants from raw water.
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页数:14
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