Measuring short-chain per- and polyfluoroalkyl substances in Central New Jersey air using chemical ionization mass spectrometry

Real-time measurements of short-chain (C < 8) per- and polyfluoroalkyl substances (PFAS) were performed in Central New Jersey air using chemical ionization mass spectrometry (CIMS). The CIMS was calibrated for C-2-C-6 perfluorinated carboxylic acids, and 4:2 and 6:2 fluorotelomer alcohols. Of these, only trifluoroacetic acid (TFA) was detected in ambient air above instrumental detection limits. However, instrumental sensitivities (and thus ambient mixing ratios) were estimated for other detected PFAS including C3H2F6O and C6HF11O3. TFA mixing ratios reached up to 0.7 parts-per-trillion by volume (pptv). Estimated C3H2F6O and C6HF11O3 mixing ratios reached the single pptv level. These latter two formulas are consistent with hexafluoroisopropanol (HFIP) and hexafluoropropylene oxide dimer acid (HFPO-DA), respectively, though they may potentially represent multiple isomers. Diel profiles of detected PFAS along with local meteorological data can provide information on potential local sources of these compounds. However, only limited discussion of potential sources was provided here given the sparse detection of these compounds above instrument detection limits. These results demonstrate the potential of online CIMS instrumentation for measuring certain PFAS in ambient outdoor air in real time at or below the pptv level. This technique also has potential for fenceline monitoring and other near-source applications.<br />