Comprehensive evaluation of the influence of PEM water electrolyzers structure on mass transfer performance based on entropy weight method

The proton exchange membrane water electrolyzer (PEMWE) has broad prospects in hydrogen production due to its green and efficient advantages. This paper comprehensively analyzes the performance and water-gas transport characteristics of PEMWE with different cell structures, in which polarization curves, flow velocity distribution, oxygen concentration, temperature, liquid water saturation, and pressure are investigated. Simultaneously, the study explores the effects of variations in inlet velocity, inlet temperature, porosity, and thickness of the anode porous transport layer (APTL) on the four flow fields. Finally, the technique for order preference by similarity to ideal solution (TOPSIS) based on entropy weight method is employed for a comprehensive evaluation of the flow fields. The results indicate that, compared to parallel flow field (PFF), sinusoidal wave flow field (SWFF), intercepted flow field (ICFF), and single-serpentine flow field (SSFF) exhibit stronger exhaust capabilities, with temperature uniformity increasing by 83.65 %, 59.24 %, and 70.15 %, respectively. However, the longer flow channel of SSFF results in a high pressure drop and lower liquid water saturation. An increase in inlet velocity leads to a decrease in temperature, causing an increase in voltage, as higher temperatures reduce activation and ohmic overpotentials. Additionally, an increase in the porosity and thickness of APTL deteriorates the polarization performance of PEMWE. The research results of this study can provide valuable assistance for the future design of PEMWE.