Oxidative [3+2] cycloaddition of triazenes and trisubstituted dichloroalkenes

被引：0

作者：

Mitsuhashi, Takuya ^{[1
]}

Kase, Daiya ^{[1
]}

Tomatsuri, Ai ^{[2
]}

Takada, Tsuyoshi ^{[2
]}

Haraguchi, Ryosuke ^{[1
,2
]}

机构：

[1] Chiba Inst Technol, Grad Sch Engn, Dept Appl Chem, Narashino, Chiba 2750016, Japan

[2] Chiba Inst Technol, Fac Engn, Dept Appl Chem, Narashino, Chiba 2750016, Japan

来源：

TETRAHEDRON LETTERS | 2024年 / 139卷

关键词：

Triazolium; Cycloaddition; Catalyst free;

D O I：

10.1016/j.tetlet.2024.154993

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1H-1,2,3-Triazolium scaffolds are used in a variety of fields including supramolecular chemistry, organometallic chemistry, and organocatalysis. In this study, an oxidative [3 + 2] cycloaddition of triazenes and trisubstituted dichloroalkenes was developed. The reaction proceeded under mild conditions to afford functionalized chloro1H-1,2,3-triazolium salts. The reaction was successfully performed on a gram scale. Moreover, a chloro-1H-1,2,3triazolium salt could be employed for nucleophilic aromatic substitution with various nucleophiles.

引用

页数：4

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