Latest Developments on Palladium- and Nickel-Catalyzed Cross-Couplings Using Aryl Chlorides: Suzuki-Miyaura and Buchwald-Hartwig Reactions

被引：0
|
作者：
Sen, Abhijit [1 ]
Yamada, Yoichi M. A. [1 ]
机构：
[1] RIKEN Ctr Sustainable Resource Sci, Saitama 3510198, Japan
来源：
SYNTHESIS-STUTTGART | 2024年
基金：
日本学术振兴会;
关键词：
palladium catalysis; nickel catalysis; cross-coupling; aryl chloride; Buchwald-Hartwig amination; Suzuki-Miyaura coupling; homogeneous catalysis; heterogeneous catalysis; OXIDATIVE ADDITION; (HETERO)ARYL CHLORIDES; RECOVERABLE CATALYSTS; HETEROARYL CHLORIDES; REUSABLE CATALYST; AMINATION; EFFICIENT; LIGANDS; NANOPARTICLES; BROMIDES;
D O I：
10.1055/a-2344-5677
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium- and nickel-catalyzed cross-couplings are powerful methods for constructing C-C and C-N bonds, particularly through Suzuki-Miyaura and Buchwald-Hartwig reactions. Although aryl iodides, bromides, and triflates are the most commonly used substrates, aryl chlorides are less frequently utilized due to their lower reactivity. However, they are appealing because they are readily available and inexpensive. This short review highlights recent developments on the Suzuki-Miyaura and Buchwald-Hartwig cross-couplings of aryl chlorides, using both homogeneous and heterogeneous catalysis with palladium and nickel.
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页数：20
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